Electrophile addition reactions

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56 Terms

1
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H-x what adds

H X

2
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H-x regiochemistry

mark

3
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H-X sterochemtrisy

forms carbocation

4
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H-X reaction

5
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H- Br/ peroxide what adds

H Br

6
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H- Br/ peroxide regiochemistry

anti mark

7
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H- Br/ peroxide sterochemistry

does not matter

8
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H- Br/ peroxide reaction

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9
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H2O, H+ what adds

H OH

10
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H2O, H+ regiochemistry

mark

11
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H2O, H+ stereochemistry

forms carbocation

12
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H2O, H+ reaction

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13
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Hg(OH2)2/ NaBH4 what adds

H OH

14
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Hg(OH2)2/ NaBH4 regiochemistry

mark

15
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Hg(OH2)2/ NaBH4 steriochemistry

anti addition

16
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Hg(OH2)2/ NaBH4 reaction

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17
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BH3/H2O2,OH- what adds

H OH

18
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BH3/H2O2,OH- regiochemistry

antimark

19
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BH3/H2O2,OH- stereochemistry

synaddition

20
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BH3/H2O2,OH- reaction

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21
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H2/PT what adds

H H

22
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H2/PT regiochemistry

does not matter

23
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H2/PT stereochemistry

syn addition

24
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H2/PT reactions

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25
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X2/CCl4 what adds

X X

26
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X2/CCl4 Regiochemistry

does not matter

27
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X2/CCl4 stereochemistry

antiaddition

28
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X2/CCl4 reaction

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29
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X2/H2O X=Cl, Br, or I what adds

X OH

30
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X2/H2O X=Cl, Br, or I regiochemisty

mark

31
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X2/H2O X=Cl, Br, or I stereochemistry

anti addition

32
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<p>what adds</p>

what adds

OH OH

33
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<p>regiochemmistry </p>

regiochemmistry

does not matter

34
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<p>stereochemistry</p>

stereochemistry

anti addition

35
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<p>reactions</p>

reactions

36
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O5O4/ H2O2 what adds

oh oh

37
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O5O4/ H2O2 regiochemistry

does not matter

38
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O5O4/ H2O2 stereochemistry

syn addition

39
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O5O4/ H2O2 reaction

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40
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cold dil KmNNO4/ H20 what adds

OH OH

41
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cold dil KmNNO4/ H20 regiochemistry

does not matter

42
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cold dil KmNNO4/ H20 stereochemistry

syn addition

43
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cold dil KmNNO4/ H20 reaction

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44
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warm concentrate KmNO4 cuts the

double bond

45
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warm concentrate KmNO4 gives

ketone and carboxylic acids

46
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warm concentrate KmNO4 gives grop

c=o

47
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warm concentrate KmNO4 reaction

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48
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O3(CH3)2S cuts the

double bond

49
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O3(CH3)2S gives

aldehydes and ketones

50
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O3(CH3)2S gives group

c=c c=o o=c

51
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syn addition

two new substituents are added to the same side

52
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anti addition

two new substituents are added to the different sides

53
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markovnikov

adds to the carbon atom of the double bond that has the greater number of hydrogen atoms

54
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anti markovnikov

adds to the carbon atom of the double bond that has the least number of hydrogen atoms

55
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hoffmans rule

elimination reaction (E2), the less substituted alkene is formed as the major product.

56
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saytzeff rule

elimination reaction (E1 or E2), the more substituted alkene is usually the major product.