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what to do when it asks you about BOND TYPES
this is not asking whether the molecule Is polar or nonpolar, but the bonds …
ionic is a metal/nonmetal
metallic is metal/metal
np covalent is two of the same nonmetal
polar covalent is ANY TWO differing nonmetals (their ENs are diff)
why is H bonding the strongest
because FON are the most electronegative
how to predict what substances would be what state at room temperature
very weak bonds, like LDF in nonpolar covalent, would be gas
very strong bonds, like ionic, would be solid (think of salt)
using IMFs, iodine would thus be a gas because its nonpolar covalent. why is it a solid at room temp?
because it has so many electrons, it’s very polarizable. so I guess polarizability trumps judging state by IMFs
steps to ranking from lowest boiling point to highest
FIRST check if there’s any metallic or ionic. metallic is strongest bond and ionic comes after that.
then check the covalents, check which ones are polar and nonpolar. check for h bonding, and know that h bonding is stronger than D/D which is stronger than LDF.
sort accordingly - if you’re in between 2, look at their electrons
what is the rule about arranging Lewis dot structures
arrange atoms around carbon OR the least EN that isn't H/halogen
so you will almost ALWAYS arrange around carbon—not the other way around
what did you keep messing up w Lewis dot
don’t say polarity or IMF if it’s an ion
does octet rule trump formal charge or other way around?
octet rule trumps formal charge. for formal charge, pick the one where the negative is on the most EN element.
properties of metallic bonds
conducts electricity
ductile, malleable, conductive
highest melting/boiling point
properties of ionic bonds
conducts electricity in water
high melting/boiling point
brittle as a solid
properties of covalent bonds
doesn’t conduct electricity
low melting/boiling point
only polar dissolves
what to remember with Lewis dot structures
DRAW RESONANCE and DRAW ION BRACKETS!!!!!!!!
how many electron domains does a double bond have
1
molecules that don’t want an octect
H - 2
Be - 4
B - 6
WHAT must be present to have a multiple bond?
carbon, oxygen, or nitrogen
what does not make more than one bond
hydrogen or halogens