Organic Chemistry (copy)

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All the reactants, conditions and reagents, in organic chemistry.

62 Terms

1

Cracking: process

breakdown of larger hydrocarbons into smaller, more usable ones

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2

hydrogen + alkene: product

alkane

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3

alkene + steam: product

product: alcohol

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4

alkene + hydrogen halide (g): product

product: major and minor haloalkane based on Markovnikov’s Rule

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5

alkene + halogen: product

product: dihaloalkane

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6

alkene + cold, dilute acidified KMnO₄: product

diol (double bond will break)

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7

alkene with non-hydrogen R groups + hot, concentrated, acidifed KMnO₄: product

ketone

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8

alkene with carbon atom with hydrogen and different R group + hot, concentrated, acidified KMnO₄: product

aldehyde further oxidized to carboxylic acid when heated under reflux

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9

alkene with carbon bonded to two hydrogen atoms + hot, concentrated, acidified KMnO₄: product

carbon dioxide + water

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10

Elimination of HX from halogenoalkane: product

alkene

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11

dehydration of alcohol

product: alkene

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12

alcohol to halogenoalkane: process

reaction: substitution

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13

halogenoalkane + NaOH (aq)

product: alcohol

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14

halogenoalkane + KCN (ethanolic): product

product: nitrile

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15

halogenoalkane + NH₃ (ammonia) in ethanol: product

product: amine

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16

halogenoalkane + silver nitrate (aq) (ethanolic): product

product: alcohol + hydrogen halide

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17

NaOH (ethanolic) + halogenoalkane: products

product: alkene + water + hydrogen halide

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18

Sn1 reaction

secondary and tertiary halogenoalkanes

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19

Sn2 reaction

primary and secondary halogenoalkanes

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20

reduction of an aldehyde: product

primary alcohol

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21

reduction of a ketone: product

secondary alcohol

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22

positive result in iodoform test

yellow precipitate of tri-iodomethane formed with the methyl hydroxyl group

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23

reduction of carboxylic acid: product

primary alcohol

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24

hydrolysis of an ester: products

product: carboxylic acid + alcohol

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25

oxidation of primary alcohols: product

product: aldehydes with distillation

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26

oxidation of secondary alcohols: product

product: ketones with distillation

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27

aldehydes with Tollens’ reagent

oxidized to produce silver mirror

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28

ketones with Tollens’ reagent

no change

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29

aldehydes with Fehling’s reagent

blue to red solution (oxidized)

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30

ketone with Fehling’s reagent

solution remains blue (no visible change)

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31

ketone and aldehydes with 2,4-DNPH

red precipitate

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32

aldehydes or ketones + HCN: product

product: hydroxy nitrile

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33

hydrolysis of nitriles: product

product: carboxylic acid

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34

cracking: reagent

Al₂O₃

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35

cracking: condition

heat at high temperature

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36

hydrogen + alkene: process

hydrogenation and electrophilic addition

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37

hydrogen + alkene: reagent and condition

reagent: Ni/Pt catalyst

condition: heat

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38

alkene + steam: process

electrophilic addition

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39

alkene + steam: reagent

H₃PO₄ (phosphoric acid) catalyst

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40

alkene + hydrogen halide (g): process

electrophilic addition

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41

alkene + hydrogen halide (g): condition

room temperature

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42

alkene + halogen: process

electrophilic addition

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43

Elimination of HX from halogenoalkane: reagent and condition

ethanolic NaOH and heat

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44

dehydration of an alcohol: reagent

heated catalyst (Al₂O₃) or concentrated acid

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45

dehydration of an alcohol: process

condenstation

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46

alcohol to halogenoalkane: reagents

reagents: HX or KBr with H₂SO₄ or H₃PO₄; or PCl₃ and heat; or PCl₅; or SOCl₂

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47

halogenoalkane + NaOH (aq): process

nucleophilic substitution

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48

halogenoalkane + KCN (ethanolic): process

nucleophilic substitution

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49

halogenoalkane + KCN (ethanolic): condition

heat under reflux

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50

halogenoalkane + NH₃ (ammonia) in ethanol: process

nucleophilic substitution

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51

halogenoalkane + NH₃ (ammonia) in ethanol: condition

heat under pressure

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52

halogenoalkane + silver nitrate (aq) (ethanolic): process

nucleophilic substitution

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53

NaOH (ethanolic) + halogenoalkane: process

elimination

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54

NaOH (ethanolic) + halogenoalkane: condition

heat

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55

reduction of an aldehyde: reagent

reagent: NaBH₄ or LiAlH₄

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56

reduction of an ketone: reagent

reagent: NaBH₄ or LiAlH₄

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57

reduction of carboxylic acid: reagent

LiAlH₄

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58

hydrolysis of an ester: reagents and conditions

dilute acid or alkali and heat

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59

oxidation of primary alcohols: reagents

reagent: acidified potassium dichromate or acidified potassium manganate (VII)

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60

oxidation of secondary alcohols: reagents

reagent: acidified potassium dichromate or acidified potassium manganate (VII)

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61

aldehydes or ketones + HCN: reagent and conditions

reagent: KCN catalyst

condition: heat under reflux

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62

hydrolysis of nitriles: reagent

reagent: dilute acid or dilute alkali followed by acidification

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