Carboxylic Acids and Esters

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14 Terms

1
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Naming carboxylic acids

<img src="https://knowt-user-attachments.s3.amazonaws.com/5b4db47b-6111-416e-a675-a4213d0f5a6b.png" data-width="100%" data-align="center" alt=""><p></p>
2
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Acidity of carboxylic acids

<img src="https://knowt-user-attachments.s3.amazonaws.com/920d67ed-b08a-42f5-91c6-084e1f637631.png" data-width="100%" data-align="center" alt=""><p></p>
3
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Solubility of carboxylic acids in water

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  • C6 actually 

  • They also stink  of vomit and body odour

<img src="https://knowt-user-attachments.s3.amazonaws.com/fc9c1498-3d96-4ead-8174-c71bde700e5f.png" data-width="100%" data-align="center" alt="knowt flashcard image"><ul><li><p>C6 actually&nbsp;</p></li></ul><ul><li><p>They also stink&nbsp; of vomit and body odour</p></li></ul><p></p>
4
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Delocalisation

<img src="https://knowt-user-attachments.s3.amazonaws.com/1cfb19b2-ab89-478a-b244-ffa4e584d044.png" data-width="100%" data-align="center" alt=""><p></p>
5
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Strength of carboxylic acids

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<img src="https://knowt-user-attachments.s3.amazonaws.com/83435f7a-b9d8-47a0-b81b-7c81391d42d8.png" data-width="100%" data-align="center" alt="knowt flashcard image"><p></p>
6
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Salt formation of carboxylic acids

Put COO- Na+

<img src="https://knowt-user-attachments.s3.amazonaws.com/39cc368e-dbad-453d-b4d4-330f32c974ee.png" data-width="100%" data-align="center" alt=""><p>Put COO- Na+ </p>
7
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Oxidation of methanoic acid

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<img src="https://knowt-user-attachments.s3.amazonaws.com/76bad440-4fa1-4750-819f-5264b53017e2.png" data-width="100%" data-align="center" alt="knowt flashcard image"><p></p>
8
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Esterification

  • That one oxygen will only have 2 bonds.

  • Concentrated acid catalyst needed

  • Name has 2 parts as there are 2 carbon chains

<img src="https://knowt-user-attachments.s3.amazonaws.com/a0d08b7b-f8c9-4b1a-8d7a-81a57c2dfb2c.png" data-width="100%" data-align="center" alt=""><img src="https://knowt-user-attachments.s3.amazonaws.com/669fa236-da0c-46c2-b2a6-fa92a1e5c223.png" data-width="100%" data-align="center" alt=""><ul><li><p>That one oxygen will only have 2 bonds.</p></li><li><p>Concentrated acid catalyst needed</p></li><li><p>Name has 2 parts as there are 2 carbon chains</p></li></ul><p></p>
9
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Uses of esters

<img src="https://knowt-user-attachments.s3.amazonaws.com/7b44f18b-6252-405a-8daf-279641c55ede.png" data-width="100%" data-align="center" alt=""><p></p>
10
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Hydrolysis of esters

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<img src="https://knowt-user-attachments.s3.amazonaws.com/12f3ec64-adff-4779-8a38-656477f1d48c.png" data-width="100%" data-align="center" alt="knowt flashcard image"><p></p>
11
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Saponification

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  • Goes to completion unlike ester hydrolysis

<p></p><img src="https://knowt-user-attachments.s3.amazonaws.com/5e592017-75d3-441d-ada1-263dac7c093e.png" data-width="100%" data-align="center" alt="knowt flashcard image"><ul><li><p>Goes to completion unlike ester hydrolysis</p></li></ul><p></p>
12
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Fats- ignore soap for now

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  • Branched= Oil

  • Straight= Fat

  • Broad group of organic molecules: fat soluble vitamins, fats, waxes, steroids

  • Carbon rich with little or no polar molecules

  • Triglycerides are composed esters. Composed of an alcohol (glycerol)- propan1,2,3-triol and three fatty acids/ carboxylic acids. Ester bond

  • Formed through condensation reactions.

<img src="https://knowt-user-attachments.s3.amazonaws.com/8fc9d031-ba9e-4157-b205-89f1ff4d577e.png" data-width="100%" data-align="center" alt="knowt flashcard image"><ul><li><p>Branched= Oil</p></li><li><p>Straight= Fat</p></li><li><p>Broad group of organic molecules: fat soluble vitamins, fats, waxes, steroids</p></li><li><p>Carbon rich with little or no polar molecules </p></li><li><p>Triglycerides are composed esters. Composed of an alcohol (glycerol)- propan1,2,3-triol and three fatty acids/ carboxylic acids. Ester bond</p></li><li><p>Formed through condensation reactions.</p></li></ul><p></p>
13
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Soap making

  • Saponification of lipids produces 3 salts of fatty acids and glycerol (alcohol).

  • Made by boiling lipids with potassium hydroxide.

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<ul><li><p>Saponification of lipids produces 3 salts of fatty acids and glycerol (alcohol).</p></li><li><p>Made by boiling lipids with potassium hydroxide.</p></li></ul><img src="https://knowt-user-attachments.s3.amazonaws.com/2e100a8a-f5db-4bc1-bae4-2ca8c895a5e9.png" data-width="100%" data-align="center" alt="knowt flashcard image"><p></p>
14
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Biodiesel

  • Can also be made from lipids

  • Triglyceride is are reacted with alcohols ( and catalysed by KOH) to form 3 methyl esters and glycerol.

  • 3 CH3OH so one for each fatty acid

<img src="https://knowt-user-attachments.s3.amazonaws.com/22e164b6-1f4f-46f5-b5c9-59eced2517ab.png" data-width="100%" data-align="center" alt=""><ul><li><p>Can also be made from lipids</p></li><li><p>Triglyceride is are reacted with alcohols ( and catalysed by KOH) to form 3 methyl esters and glycerol.</p></li><li><p>3 CH3OH so one for each fatty acid</p></li></ul><p></p>