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What is a molar enthalpy of formation (ΔH°f)
It’s the enthalpy change when one mole of a compound forms from its elements in their standard states.
What are the units of molar enthalpy of formation
kJ/mol
What is the enthalpy of formation of any element in its standard state
0 kJ/mol
What does “one mole” in the definition mean
The reaction must form exactly 1 mole of the compound (even if that means using fractions in the equation).
Write the formation equation for oxygen gas, O₂(g).
It’s an element in its natural form, so no formation reaction — ΔH°f = 0.
How can molar enthalpies of formation be shown visually
As an enthalpy change diagram, where: Y-axis = chemical potential energy. The height difference = ΔH of formation
How does this differ from a potential energy diagram
Potential Energy Diagram → shows reaction progress and activation energy. Formation Enthalpy Diagram → shows total enthalpy differences between compounds and their elements
What is ΔH°f used for
To calculate enthalpy changes of chemical reactions, especially when calorimetry data isn’t available.