CHEM 108 - Final Flashcards

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Dehydration

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37 Terms

1

Dehydration

OH → C=C

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2

Hydration

C=C → OH

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3

Hydrolysis

Thioester → Carboxylic acid or carboxylate

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4

Isomerization

Shuffling things around

Same formula but different structure

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5

Oxidation

NAD - alcohol → ketone

FAD - alkane → alkene

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6

Oxidation/decarboxylation

Carboxylate → Ketone + CO2

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7

Phosphate transfer

PiO-C → HO-C + ATP

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8

Phosphorylation

HO-C-C → PiO-C-CH

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9

Reduction

NADH - O=C → HO-C

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10

NADH

Reduce

O=C → HO-C

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11

NAD

Oxidize

HO-C → O=C

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12

FAD

Oxidize

C-C → C=C

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13

FADH2

None

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14

Co-SH

Carboxylate → Acetyl CoA

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15

Secondary alcohol

Oxidation

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16

Apha-keto acid

Oxidation/decarboxylation

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17

Thioester

Hydrolysis

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18

Alpha-beta alkene

Hydration

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19

Oxidizing agent

Causes other substance to be oxidized

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20

Reducing agent

Causes other substance to be reduced

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21

Coenzymes that enter ETC

NADH, FADH2

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22

Complex I

Uses NADH

Pushes H+

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23

Complex II

Uses FADH2

Doesn’t push H+

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24

Complex III

Cyt C

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25

Complex IV

O2 → H2O

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26

Complex I, III, IV

Push H+ into intermembrane space

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27

Intermembrane space

High H+

Low pH

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28

Matrix

Low H+

High pH

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29

Glycolysis

Glucose, ATP → ATP, NADH

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30

Citric acid cycle

Acetyl CoA → NADH, FADH2, GTP

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31

Beta-oxidation of fatty acids

Fatty acid, ATP → Acetyl CoA, FADH2, NADH

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32

Aerobic conditions

Pyruvate oxidized into acetyl CoA

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33

Anaerobic conditions

Pyruvate reduced into lactic acid

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34

NADH

2.5 ATP

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35

FADH2

1.5 ATP

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36

Glucose

32 ATP

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37

Fatty acid

8 + (#C/2 - 1)x14

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