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Solid
Particle arrangement
Particles tightly packed, fixed shape, low energy
Liquid
Particle arrangement
Particles close but able to flow, no fixed shape
Gas
Particle arrangement
Particles far apart, moving fast, high energy
Melting
Solid → liquid
Freezing
Liquid → solid
Evaporation/Boiling
Liquid → gas
Condensation
Gas → liquid
Sublimation
Solid → gas
Solvent
Substance that dissolves a solute
Solute
Substance dissolved in a solvent
Solution
Mixture of solute + solvent
Saturated solution
Maximum solute dissolved
Solubility - measured in:
g of solute per 100 g of solvent
Simple distillation
Separates solvent from solution
Fractional distillation
Separates liquids by boiling point
Filtration
Separates insoluble solid from liquid
Crystallisation
Obtains soluble solid from solution
Paper chromatography
Separates soluble substances
Rf value
Distance travelled by substance ÷ distance travelled by solvent
Reason for similarities within groups in a pTable
Same number of outer electrons
Noble gases reactivity
Unreactive due to full outer shell
Metals
Conduct electricity, form basic oxides
Silver ion
Ag⁺
Copper(II) ion
Cu²⁺
Iron(II) ion
Fe²⁺
Iron(III) ion
Fe³⁺
Lead(II) ion
Pb²⁺
Zinc ion
Zn²⁺
Hydrogen ion
H⁺
Hydroxide ion
OH⁻
Ammonium ion
NH₄⁺
Carbonate ion
CO₃²⁻
Nitrate ion
NO₃⁻
Sulfate ion
SO₄²⁻
Ionic compounds properties
High mp/bp, conduct when molten/aqueous
Simple covalent properties
Low mp/bp, no conductivity
Giant covalent properties
Very high mp/bp
Diamond
Hard, no conductivity
Graphite
Conducts, soft/slippery
C60 fullerene
Low mp, molecular
Anion
Negative ion → anode
Cation
Positive ion → cathode
Reaction at cathode
Reduction
Reaction at anode
Oxidation
Conductivity of ionic compounds
Only when molten/aqueous
PbBr₂ electrolysis
Pb at cathode, Br₂ at anode
Aqueous NaCl electrolysis
H₂ at cathode, Cl₂ at anode, NaOH produced
Dilute H₂SO₄ electrolysis
H₂ at cathode, O₂ at anode
CuSO₄ electrolysis
Cu at cathode, O₂ at anode
General reaction: metal + water—> ?
metal hydroxide + hydrogen
Reactivity trend Group 1
Increases down group
Lithium with water observation
Steady fizzing
Sodium with water observation
Fast fizzing, melts
Potassium with water observation
Lilac flame
Reactivity explanation group 1
Outer electron further → more easily lost
Chlorine appearance
Pale green gas
Bromine appearance
Orange
Iodine appearance
Grey solid, purple vapour
Reactivity trend Group 7
Decreases down group
Displacement rule
More reactive halogen displaces less reactive halide
Nitrogen % in air
78%
Oxygen % in air
21%
Argon % in air
1%
CO₂ % in air
0.04%
Mg + O₂
Forms white MgO
Hydrogen + oxygen
Forms water
Sulfur + oxygen
Forms SO₂
Greenhouse gas
CO₂, Methane, SO2
contributes to climate change
Thermal decomposition of carbonates
Metal + carbonate —>
Metal oxide + CO₂
Reactivity series
K > Na > Li > Ca > Mg > Al > Zn > Fe > Cu > Ag > Au
Rusting conditions
Oxygen + water
Rust prevention (barrier)
Paint, grease
Rust prevention (galvanising)
Zinc coating
Rust prevention (sacrificial)
More reactive metal
Oxidation
Gain of oxygen / loss of electrons
Reduction
Loss of oxygen / gain of electrons
Oxidising agent
Causes oxidation, is reduced
Reducing agent
Causes reduction, is oxidised
How are most metals obtained
Extracted from ores
Unreactive metals found:
Found as elements
Iron extraction
Carbon reduction
Aluminium extraction
Electrolysis
Alloy
Mixture of metals
Why are alloys harder
Layers distorted by different atom sizes
Mild steel
Malleable/flexible
High carbon steel
brittle
Stainless steel
Corrosion resistant
Litmus
Red in acid, blue in alkali
Phenolphthalein
Colourless in acid, pink in alkali
Methyl orange
Red in acid, yellow in alkali
Strongly acidic pH range
0-3
weakly acidic pH
4-6
Neutral pH
7
weakly alkaline
8-10
strongly alkaline pH
11-14
Acid
Source of H⁺
Alkali
Source of OH⁻
Acid definition
Proton donor
Base definition
Proton acceptor
All nitrates
Soluble