Solvents, Nucleophiles and Bases to Memorize (copy)

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44 Terms

1
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NaOH

Strong Nucleophile AND Strong Base

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KOH

Strong Nucleophile AND Strong Base

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NaOMe

Strong Nucleophile AND Strong Base

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NaOEt

Strong Nucleophile AND Strong Base

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NaO-R

Strong Nucleophile AND Strong Base

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NaCC-R

Strong Nucleophile AND Strong Base

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acetylide anion

Strong Nucleophile AND Strong Base

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NaNH2

Strong Nucleophile AND Strong Base

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NaNH-R

Strong Nucleophile AND Strong Base

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NaN-R2

Strong Nucleophile AND Strong Base

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LiCH3

Strong Nucleophile AND Strong Base

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R-Li

Strong Nucleophile AND Strong Base

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NaI

Strong Nucleophile Weak Base

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LiBr

Strong Nucleophile Weak Base

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KI

Strong Nucleophile Weak Base

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NaN3

Strong Nucleophile Weak Base

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R-SH

Strong Nucleophile Weak Base

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H2S

Strong Nucleophile Weak Base

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RS(-)

strong nucleophile weak base

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NaCN

moderate base, strong nucleophile

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KCN

moderate base, strong nucleophile

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<p>tBuLi</p>

tBuLi

Strong base, weak nucleophile

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(CH3)3CLi

Strong base, weak nucleophile

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KOtBu

Strong base, weak nucleophile

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KOC(CH3)3

Strong base, weak nucleophile

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LDA

Strong base, weak nucleophile

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LiN(CH(CH3)2)2)

Strong base, weak nucleophile

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<p>DBU</p>

DBU

Strong base, weak nucleophile

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<p>DBN</p>

DBN

Strong base, weak nucleophile

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H2O

Weak Nucleophile, Weak Base

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MeOH

Weak Nucleophile, Weak Base

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EtOH

Weak Nucleophile, Weak Base

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<p>Water</p>

Water

polar protic

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<p>alcohols</p>

alcohols

polar protic

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<p>acetic acid</p>

acetic acid

polar protic

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<p>H3C=O-OH</p>

H3C=O-OH

polar protic

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<p>amines</p>

amines

polar protic

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<p>DMF</p>

DMF

polar aprotic

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<p>DMSO</p>

DMSO

polar aprotic

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<p>Acetonitrile</p>

Acetonitrile

polar aprotic

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<p>HMPA</p>

HMPA

polar aprotic

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<p>acetone</p>

acetone

polar aprotic

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<p>diethyl ether</p>

diethyl ether

polar aprotic

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<p>THF</p>

THF

polar aprotic