OIA1012 ALKENES

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23 Terms

1
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Q:What are alkenes?

A:Alkenes are unsaturated hydrocarbons containing at least one C=C double bond.

2
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Explain free radical addition of HBr.

If HBr, then H is added to less substituted C atom (anti-Markovnikov rule), producing more highly substituted carbocation intermediate.

<p>If HBr, then H is added to less substituted C atom (anti-Markovnikov rule), producing more highly substituted carbocation intermediate.</p>
3
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Q:What is the general formula for alkenes?

A:The general formula for alkenes is CₙH₂ₙ.

4
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Q:What type of isomerism is associated with alkenes?

A:Alkenes exhibit geometric isomerism due to restricted rotation around the C=C bond.

5
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Q:How do you name an alkene?

A:Identify the longest carbon chain containing the C=C bond, replace the -ane ending with -ene, and number the chain to indicate the position of the double bond.

6
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Q:What is Markovnikov’s rule?

A:In the addition of an electrophile to a C=C bond, the electrophile adds to the less substituted carbon atom.

7
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Q:What is the effect of alkyl substitution on the stability of carbocation intermediates?

A:Reactivity increases with increasing alkyl substitution due to electron-donating effects, stabilizing the carbocation.

8
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Q:What are addition reactions in alkenes?

A:Addition reactions involve the addition of atoms or groups across the C=C bond, resulting in the formation of saturated products.

9
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Q:What is the outcome of the ionic addition of halogens to alkenes?

A:The outcome is the formation of vicinal dibromides, such as trans-1,2-dibromocyclohexane from cyclohexene.

10
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Q:Describe the free radical addition of halogens.

A:Free radical addition involves the formation of radicals and occurs under light conditions, leading to substitution at the allylic position.

<p>A:Free radical addition involves the formation of radicals and occurs under light conditions, leading to substitution at the allylic position.</p>
11
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Q:What is the role of KMnO₄ in alkenes?

A:KMnO₄ is a powerful oxidizing agent used for oxidative cleavage of C=C bonds.

12
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Q:Explain the concept of ozonolysis.

A:Ozonolysis is the oxidative cleavage of C=C bonds using ozone (O₃), resulting in carbonyl compounds.

<p>A:Ozonolysis is the oxidative cleavage of C=C bonds using ozone (O₃), resulting in carbonyl compounds.</p>
13
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Q:What is the significance of hydrogenation in alkenes?

A:Hydrogenation is the addition of hydrogen across the C=C bond, converting alkenes into alkanes, often used in food processing.

<p>A:Hydrogenation is the addition of hydrogen across the C=C bond, converting alkenes into alkanes, often used in food processing.</p>
14
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Q:What are conjugated dienes?

A:Conjugated dienes are compounds with two C=C bonds that are separated by a single bond, allowing for delocalization of π electrons.

<p>A:Conjugated dienes are compounds with two C=C bonds that are separated by a single bond, allowing for delocalization of π electrons.</p>
15
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What is product of bromine/halogen acid addition in conjugated dienes?

Mainly 1,4-addition products.

<p>Mainly 1,4-addition products.</p>
16
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Show mechanism of addition of hypohalous acid (halogen in H2O).

  1. C=C attack Cl form carbocation & other Cl form radical

  2. water attack carbocation

  3. Cl radical attack H of H2O and the bond attack O+

  4. H2O+ form OH

<ol><li><p>C=C attack Cl form carbocation &amp; other Cl form radical </p></li><li><p>water attack carbocation </p></li><li><p>Cl radical attack H of H2O and the bond attack O+</p></li><li><p>H2O+ form OH</p></li></ol>
17
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Q:What is the Diels-Alder reaction?

A:The Diels-Alder reaction is a cycloaddition reaction between a diene and a dienophile, producing a cyclic compound.

<p>A:The Diels-Alder reaction is a cycloaddition reaction between a diene and a dienophile, producing a cyclic compound.</p>
18
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Q:How do alkenes undergo auto-oxidation?

A:Alkenes can undergo auto-oxidation at the allylic position when exposed to air or light, leading to allylic oxidation products.

<p>A:Alkenes can undergo auto-oxidation at the allylic position when exposed to air or light, leading to allylic oxidation products.</p>
19
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Q:What is the significance of trans fatty acids formed from partial hydrogenation?

A:Trans fatty acids can raise blood cholesterol levels and contribute to coronary heart disease.

20
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Q:Describe the process of polymerization of alkenes.

A:Polymerization involves the radical-induced reaction of alkenes at high temperatures and pressures to form long-chain polymers like polyethylene.

21
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Q:What are the physical properties of alkenes?

A:Alkenes resemble alkanes in physical properties, being gases or low-boiling liquids, and are insoluble in polar solvents.

22
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Q:Explain the role of electron-withdrawing groups in alkene reactivity.

A:Electron-withdrawing groups decrease the stability of carbocation intermediates, reducing the reactivity of alkenes except for phenyl as carbocation intermediate due to resonance stabilisation .

<p>A:Electron-withdrawing groups decrease the stability of carbocation intermediates, reducing the reactivity of alkenes except for phenyl as carbocation intermediate due to resonance stabilisation .</p>
23
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Q:What is the biological significance of retinol (Vitamin A)?

A:Retinol is crucial for vision and is sensitive to oxidation, forming inactive dimers upon exposure to light.

<p>A:Retinol is crucial for vision and is sensitive to oxidation, forming inactive dimers upon exposure to light.</p>