CHEM-UA 125 Chapter 6 Vocabulary

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30 Terms

1

biomass fuel

A fuel composed of biological materials such as plant and animal matter.

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2

calorie (cal)

A unit of energy defined as exactly 4.184 joules; originally defined as the heat needed to raise the temperature of 1 g of water 1°C (from 14.5°C to 15.5°C).

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3

calorimeter

A device used to measure the heat released or absorbed by a physical or chemical process taking place within it.

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4

change in enthalpy (ΔH)

The change in the system’s internal energy plus the product of the constant pressure and the change in volume: ΔH = ΔE + PΔV; alternatively, the heat lost or gained at constant pressure: ΔH = qP.

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5

endothermic process

A process that occurs with an absorption of heat from the surroundings and therefore an increase in the enthalpy of the system (ΔH > 0).

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6

enthalpy (H)

A thermodynamic quantity that is equal to the system’s internal energy plus the product of the pressure and volume.

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7

enthalpy diagram

A graphic depiction of the enthalpy change of a system.

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8

exothermic process

A process that occurs with a release of heat to the surroundings and therefore a decrease in the enthalpy of the system (ΔH < 0).

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9

formation equation

An equation in which 1 mole of a compound forms from its elements.

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10

fossil fuel

Any fuel, including coal, petroleum, and natural gas, derived from the products of the decay of dead organisms.

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11

heat (q)

(also thermal energy) The energy transferred between objects because of a difference in their temperatures only.

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12

heat capacity (C)

The quantity of heat required to change the temperature of an object by 1 K.

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13

Hess’s law

A law stating that the enthalpy change of an overall process is the sum of the enthalpy changes of the individual steps.

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14

internal energy (E)

The sum of the kinetic and potential energies of all the particles in a system.

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15

joule (J)

The SI unit of energy; 1 J = 1 kg · m2/s2.

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16

law of conservation of energy

(also first law of thermodynamics) A basic observation that the total energy of the universe is constant; thus, ΔEuniverse = ΔEsystem + ΔEsurroundings = 0.

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17

molar heat capacity (Cm)

The quantity of heat required to change the temperature of 1 mol of a substance by 1 K.

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18

photovoltaic cell

A device capable of converting light directly into electricity.

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19

pressure-volume work

(also PV work) A type of mechanical work done when a volume change occurs against an external pressure.

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20

specific heat capacity (c)

The quantity of heat required to change the temperature of 1 gram of a substance or material by 1 K.

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21

standard enthalpy of formation ΔH°f

(also standard heat of formation) The enthalpy change occurring when 1 mol of a compound forms from its elements with all components in their standard states.

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22

standard enthalpy of reaction ΔH°rxn

(also standard heat of reaction) The enthalpy change that occurs during a reaction when all components are in their standard states.

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23

standard state

A set of specific conditions used to compare thermodynamic data: 1 atm for gases behaving ideally, 1 M for dissolved species, or the pure substance for liquids and solids.

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24

state function

A property of a system determined only by the system’s current state, regardless of how it arrived at that state.

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25

surroundings

All parts of the universe other than the system being considered.

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26

system

The defined part of the universe under study.

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27

thermochemical equation

A balanced chemical equation that includes the enthalpy change for the reaction

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28

thermochemistry

The branch of thermodynamics that focuses on the heat involved in chemical and physical change.

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29

thermodynamics

The study of energy and its transformations.

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30

work (w)

The energy transferred when an object is moved by a force.

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