catalyzes shifting of a chemical group from one position to another
movement of phosphate by phosphoglycerate mutase
helps prepare substrate to transfer this group to ADP to make ATP
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Glycolysis step one?
glucose is phosphorylated by ATP to form sugar phosphate
glucose plus ATP → glucose 6 phosphate plus ADP and H+
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Glycolysis step two?
reversible rearrangement of the chemical structure (isomerization) moves the carbonyl oxygen from carbon 1 to carbon 2 forming a ketose from an aldose sugar
glucose 6 phosphate → fructose 6 phosphate
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Glycolysis step three?
new hydroxyl group on carbon 1 is phosphorylated by ATP, in preparation for the formation of two three-carbon sugar phosphates, entry of sugars into glycolysis is controlled at this step, through regulation of the enzyme phosphofructokinase
Fructose 6-phosphate plus ATP → Fructose 1,6-Biphosphate plus ADP and H+
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Glycolysis steps 1-3 is dedicated to?
energy investment
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Glycolysis step 4?
6 carbon sugar is cleaved to produce two three carbon molecules, only the glyceraldehyde 3-phosphate can proceed immediately through glycolysis
two molecules of glyceraldehyde 3-phosphate are oxidized, the energy generation phase of glycolysis begins, NADH and a new high energy anhydride linkage to phosphate are formed
glyceraldehyde 3 phosphate + NAD+ and Pi → 1,3-biphosphglycerate + NADH and H+
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Glycolysis step 7?
transfer to ADP of high energy phosphate group that was generated in step 6 forms ATP
1,3-biphosphglycerate + ADP → 3-phosphoglycerate + ATP
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glycolysis step 8?
remaining phosphate ester linkage in 3-phosphoglycerate which has a relatively low free energy of hydrolysis, is moved from carbon 3 to carbon 2 to form 2-phosphoglycerate
3-phosphoglycerate → 2-phosphoglycerate
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glycolysis step 9?
removal of water from 2-phosphoglycerate creates a high energy enol phosphate linkage
2-phosphoglycerate → phosphoenolpyruvate + H2O
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glycolysis step 10?
transfer to ADP of the high energy phosphate group that was generated in step 9 forms ATP
phosphoenolpyruvate + ADP and H+ → pyruvate + ATP
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what is glycolysis step 6-10 dedicated to?
energy generation steps
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where does pyruvate go after glycolysis?
mitochondria
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Fermentation
biochemical reaction that extracts energy from carbohydrates without using oxygen
products include ethanol, hydrogen gas, and lactic acid
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End product of electron transport chain?
**water and ATP**
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photosynthesis
light driven process in which CO2 is fixed to yield carbohydrates
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Is CO2 reduced or oxidized during photosynthesis?
reduced
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Is water reduced or oxidized during photosynthesis?
oxidized
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Elucidation of photosynthesis?
notion that plants obtain nourishment from such insubstantial things as light and air took nearly two centuries to develop
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violet has the shortest or the longest wavelength?
shortest
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red has the shortest or the longest wavelength?
longest
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light has properties of what?
waves and particles
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pigment
substance that absorbs light
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chorophyll
absorbs light in violet and blue wavelengths also red
reflects green
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when chlorophyl absorb light, electrons are temporarily boosted to a..
higher energy level: excited state
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what are the three possible fates of electrons as they return to a lower energy level?
energy is converted to heat or released as a photo (fluorescence), energy is transferred from the excited chlorophyll to a neighboring chlorophyll (resonance energy transfer), high energy electron is transferred to neighboring molecules (electron acceptor)
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Chlorophyll a
occurs in all photosynthesis eukaryotes and cyanobacteria
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chlorophyll b
occurs in plants and algae, has different absorption spectrum
an accessory pigment
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accessory pigment
not directly involved in photosynthesis but helps, passes energy to chlorophyll a
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carotenoids and phycobilins
an accessory pigment, passes energy to chlorophyll a
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2 sets of reactions of photosynthesis
light and carbon fixation (Calvin cycle) reaction
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light reactions
ATP is produced from AADP and inorganic phosphate using transfer of electrons and production of NADPH
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Calvin fixation reactions
energy of ATP is used to link carbon dioxide covalently to an organic molecule and the reducing power of NADPH is used to reduce to a simple sugar
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how many photosystems are involved in light reactions?
2
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photosystems
two closely linked components: antennae and reaction complex
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antennae complex
gather light energy and funnel it to the reaction center
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reaction complex
contains a special pair of chlorophyll a molecules that are capable of actually using the energy
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photosystem + LHC
photosystem complex
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light harvesting complex (LHC)
usually associated with a photosystem to allow for even greater light gathering power
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can photosystem 1 work independently of photosystem 2?
yes
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cyclic electron flow
instead of electrons being passed to NADP+, they are shunted to an accepter in the ETC between PS1 and PS2
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cyclic phosphorylation
process of photophosphorylation in which an electron expelled by the excited photo-center is returned to it after passing through a series of electron carriers
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noncyclic phosphorylation
two-stage process involving two different chlorophyll photosystems in the thylakoid membrane
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Calvin cycle starts with?
ribulose 1,5-biphosphate (RuBP)
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first step of calvin cycle is catalyzed by?
rubisco
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second step of calvin cycle
reduction of 3 phosphoglycerate to glyceraldehyde 3 phosphate
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third step of calvin cycle
regeneration of RuBP
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plants are what kind of growers?
indeterminate
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what are the name of plant hormones
phytohormones
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phytohormones
used for cellular communication in plants
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what are the 3 basic elements for a plant hormone?
transport, induced chemical response, synthesis in one part for the plant
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(True/False): phytohormones are synthesized in one location in the plant