Organic Chemistry II Reagents

benzene + fuming H2SO4

benzene + HSO3 (benzenesulforic acid)

benzene + 1) ChCl 2) AlCl3

benzene + CH3 (toulene)

benzene + 1) HNO3 2) H2SO4

benzene + NO2 (nitrobenzene)

benzene + 1) Br2 2)AlBr3

benzene + Br (bromobenzene)

benzene + 1) Cl2 2)AlCl3

benzene + Cl (chlorobenzene)

benzene + propionyl chloride

Propiophenone (1-phenylpropan-1-one)

nitrobenzene + 1) ZnHCl 2) NaOH

benzene + NH2 (aniline)

Propiophenone + 1) Zn(Hg), HCl 2) heat

benzene + C3H8 (propylbenzene)

toulene +xs NBS

benzene + CBr3 (phenylbromethane)

toulene +1)KMNO4 2) H2O, heat 3) H30+

benzene + carboxylic acid (benzoic acid)

carboxylic acid + 1) NaOH 2) CH3COCl 3) heat

acid anhydride

formation of carboxylic acid from acid anhydride

acid anydride + 1) NaOH 2) CH3COCl 3) H2O

acid anhydride + ROH

ester

acid anhydride + xs NH3

primary amide

acid anhydride + xs R2NH

tertiary amide

acid anhydride + xs RNH2

secondary amide

acid anhydride + 1) xs LiAlH4 2) H3O+

primary alcohol

acid anhydride + 1) LiAl(OR)3H 2) H3O+

aldehyde

acid anhydride + 1) RMgBr

tertiary alcohol

acid anhydride + 1) R2CuLi

ketone