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Christ Pantokrator, early 6th century, encaustic on panel, Saint Catherine, Sinai,Egypt
encaustic
heated wax mixed with pigments and applied to a wooden surface; applied in layers and manipulated by scraping, texturing, layering, reheating, etc; creates greater sense of naturalism.


Cimabue, Madonna Enthroned (Maesta), ca 1280-1290, tempera on panel
tempera
a painting medium made of egg yolks and water; pigments were ground together with this mixture. `
gold ground
foil or pigment applied to red bole (clay-based surface of prepared canvas)

The Verification of the Stigmata, 1288-1297, fresco,

Ambrogio Lorenzetti,The Annunciation, 1344, tempera on wood

Ambrogio Lorenzetti, Martyrdom of the Franciscans, mid 1340s, fresco


Andrea Pisano, Panel showing “Architecture” from the east side of the Campanile of Florence, 1348-1350, marble

Nanni di Banco, Quattro Saint Coronati, 1408-13, marble, florence