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Ionic:
Properties:
High melting and boiling points
Hard and brittle (breaks easily when pressure is applied)
Conducts electricity only in molten state or when dissolved in water (due to free-moving ions)
Soluble in water
Forms crystal lattice structures
High lattice energy due to strong electrostatic forces between ions
Covalent:
Properties:
Low melting and boiling points
Soft or liquid (depending on molecular size)
Does not conduct electricity (no free-moving ions or electrons)
Solubility varies (polar covalent compounds are soluble in water, non-polar covalent compounds are not)
Low lattice energy compared to ionic compounds
Electrons are shared between atoms, resulting in distinct molecular shapes (polar or non-polar)
Polar Covalent:
Properties:
Moderate melting and boiling points
Soft to moderate hardness
Does not conduct electricity in solid form
Soluble in polar solvents (e.g., water)
Unequal sharing of electrons, causing partial positive and negative charges on the atoms
Intermediate electronegativity difference (usually between 0.5 and 1.7)
Non-Polar Covalent:
Properties:
Low melting and boiling points
Soft
Does not conduct electricity (no free ions or electrons)
Insoluble in water (soluble in non-polar solvents)
Equal sharing of electrons between atoms
Electronegativity difference is less than 0.5
Metallic:
Properties:
High melting and boiling points
Good conductors of electricity (due to free-moving "sea of electrons")
Malleable and ductile (can be shaped into wires and sheets)
Lustrous (shiny) appearance
Moderate to high hardness
Electrons are delocalized, forming a "sea" of electrons around metal ions that allows conductivity and malleability
Covalent Network (Giant Covalent Structures):
Properties:
Very high melting and boiling points
Very hard
Do not conduct electricity (unless they are graphite or graphene)
Insoluble in most solvents
Atoms are covalently bonded in a continuous network (e.g., diamond, quartz)
Strong bonds extend throughout the structure
Solid Molecular:
Properties:
Low melting and boiling points (generally lower than ionic or covalent network solids)
Soft (easily deformed)
Non-conductive (no free ions or electrons)
Soluble in non-polar solvents, but insoluble in polar solvents (depends on polarity of the molecules)
Held together by weak intermolecular forces, such as London dispersion forces, dipole-dipole forces, or hydrogen bonding (depending on the substance)
Distinct molecules: The solid consists of molecules held together by intermolecular forces, rather than a network of atoms or ions.
Properties:
Low melting and boiling points (generally lower than ionic or covalent network solids)
Soft (easily deformed)
Non-conductive (no free ions or electrons)
Soluble in non-polar solvents, but insoluble in polar solvents (depends on polarity of the molecules)
Held together by weak intermolecular forces, such as London dispersion forces, dipole-dipole forces, or hydrogen bonding (depending on the substance)
Distinct molecules: The solid consists of molecules held together by intermolecular forces, rather than a network of atoms or ions.