properties of crystals

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7 Terms

1
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Ionic:

  • Properties:

    • High melting and boiling points

    • Hard and brittle (breaks easily when pressure is applied)

    • Conducts electricity only in molten state or when dissolved in water (due to free-moving ions)

    • Soluble in water

    • Forms crystal lattice structures

    • High lattice energy due to strong electrostatic forces between ions

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Covalent:

Properties:

  • Low melting and boiling points

  • Soft or liquid (depending on molecular size)

  • Does not conduct electricity (no free-moving ions or electrons)

  • Solubility varies (polar covalent compounds are soluble in water, non-polar covalent compounds are not)

  • Low lattice energy compared to ionic compounds

  • Electrons are shared between atoms, resulting in distinct molecular shapes (polar or non-polar)

3
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Polar Covalent:

  • Properties:

    • Moderate melting and boiling points

    • Soft to moderate hardness

    • Does not conduct electricity in solid form

    • Soluble in polar solvents (e.g., water)

    • Unequal sharing of electrons, causing partial positive and negative charges on the atoms

    • Intermediate electronegativity difference (usually between 0.5 and 1.7)

4
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Non-Polar Covalent:

  • Properties:

    • Low melting and boiling points

    • Soft

    • Does not conduct electricity (no free ions or electrons)

    • Insoluble in water (soluble in non-polar solvents)

    • Equal sharing of electrons between atoms

    • Electronegativity difference is less than 0.5

5
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Metallic:

Properties:

  • High melting and boiling points

  • Good conductors of electricity (due to free-moving "sea of electrons")

  • Malleable and ductile (can be shaped into wires and sheets)

  • Lustrous (shiny) appearance

  • Moderate to high hardness

  • Electrons are delocalized, forming a "sea" of electrons around metal ions that allows conductivity and malleability

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Covalent Network (Giant Covalent Structures):

Properties:

  • Very high melting and boiling points

  • Very hard

  • Do not conduct electricity (unless they are graphite or graphene)

  • Insoluble in most solvents

  • Atoms are covalently bonded in a continuous network (e.g., diamond, quartz)

  • Strong bonds extend throughout the structure

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Solid Molecular:

  • Properties:

    • Low melting and boiling points (generally lower than ionic or covalent network solids)

    • Soft (easily deformed)

    • Non-conductive (no free ions or electrons)

    • Soluble in non-polar solvents, but insoluble in polar solvents (depends on polarity of the molecules)

    • Held together by weak intermolecular forces, such as London dispersion forces, dipole-dipole forces, or hydrogen bonding (depending on the substance)

    • Distinct molecules: The solid consists of molecules held together by intermolecular forces, rather than a network of atoms or ions.

Properties:

  • Low melting and boiling points (generally lower than ionic or covalent network solids)

  • Soft (easily deformed)

  • Non-conductive (no free ions or electrons)

  • Soluble in non-polar solvents, but insoluble in polar solvents (depends on polarity of the molecules)

  • Held together by weak intermolecular forces, such as London dispersion forces, dipole-dipole forces, or hydrogen bonding (depending on the substance)

  • Distinct molecules: The solid consists of molecules held together by intermolecular forces, rather than a network of atoms or ions.