Percentage yield + atom economy

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1
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Why do reactions not produce 100% yield of the desired products?

  • Incomplete reaction

  • Products lost during purification steps (e.g. distillation or recrystallisation)

  • Products lost during transfer between apparatus

  • Impure starting material

  • Side reacting producing different products

2
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Percentage yield =

(actual yield / theoretical yield) x100

3
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What is theoretical yield?

The maximum possible amount of product

4
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What is actual yield?

The amount of product obtained from the reaction

5
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How is the theoretical yield calculated using the chemical equation?

Using the limiting reagent

6
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What is percentage yield?

A measure of the efficiency of the process.

7
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What does atom economy measure?

The efficiency of the chemical reaction

8
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Atom economy =

(molecular mass of desired products / sum of molecular masses of all products) x 100

9
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What will the atom economy of an addition reaction be + why?

100% as it only gives one product

10
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How can atom economy be improved?

  • Use the waste products

  • Use alternate reaction with a higher atom economy

  • Choose spectator ions with a lower Ar

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