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The particle theory of matter
Discovered by John Dalton
Matter is anything that has mass
All matter is made up of tiny particles that have empty spaces between them
Different substances are made up of different particles
Particles are in constant motion
Particles move faster with heat increase
The degree that particles are attracted to each other is different in different substances
States of Matter
Solids are rigid and have definite shapes
Their atoms are usually: closely packed together, regularly arranged, little movement, do not expand with heat, and extremely hard to compress
Liquids flow and take the shape of a container
Molecules in liquids are randomly oriented, expand slightly with heat, compress slightly under pressure
Gas less dense than liquids and solids, occupy all parts of a container, can expand infinitely, and is easily compressed
Distinguishing between a Compound and an Element
Element: can be found on the periodic table
Compound: made with 2+ elements
Chemical and Physical Properties of Matter
Physical:
Gives us information about what a substance is like
They are characteristics of a substance that can be determined without changing the composition of that substance
Make observations using our 5 senses
Chemical:
A property of a substance that describes its ability to undergo changes to its composition to produce one or more new substances
Include how a substance interacts with other substances such as water oxygen or acids
Can only be observed when a chemical change occurs
Qualitative and Quantitative Properties
Qualitative observation: not measured and does not have a numerical value
E.g. colour, odour, texture
Quantitative: measured and has a numerical value
E.g temperature, height, mass
Characteristic physical properties
A physical property that is unique to a substance and that can be used to identify it.
It can be determined without changing the composition of the sample
Density: ratio of mass to volume, usually in g/㎤ and g/mL
D = m/V m = DV V = m/D
Melting point: solid to liquid
Freezing point: liquid to a solid
Boiling point: liquid to gas
Electric conductivity
Physical and chemical change
Physical Change can usually be reversed
Is a change in which the composition of the substance remains unaltered and no new substances are produced
E.g. when ice melts into liquid or when paper is folded into an airplane
Chemical change always results in the formation of one or more new substances
The original substance does not disappear
The components of the original substance are simply rearranged in the process of forming a new substance
Evidence of a Chemical Change
A change in colour: has formed a different colour than the original substance
A change in odour: formed a new detectable odour
Production of gas: new substance is produced in the form of gas
Bubbles are visible, not caused by heating
Change in temperature or light: energy is released (exothermic) or absorbed (endothermic) during a chemical change
E.g. photosynthesis vs cellular respiration
Formation of a precipitate: does not dissolve in the mixture and shows up as a solid called precipitate
Mixtures
Made up of 2+ different kinds of particles
Solutions (Homogeneous Mixture): uniform mixtures, particles combine to make a pure substance appearance
Mechanical Mixture (Heterogeneous Mixtures): can distinguish (visible) between the two particles
Alloys
A metal by itself is a pure substance because it is only one type of particle
But when metals are mixed together they are called alloys, which are solid solutions (Homogeneous) of 2+ metals
Made by melting down pure metals and physical mixing them to make a solution
The Periodic Table Locations
They have similar physical and chemical properties
Metals: located on the left central side of the staircase
Solid, Luster/shiny, good electrical conductors, easy to shape (malleable)
Nonmetals: on the right upper portion of the periodic table
Mostly gas, dull powdery solids, or bromine as the only liquid, poor conductors of electricity, hard to shape and brittle
Metalloids: along the zigzag line dividing metals and nonmetals
Properties of both metals and nonmetals
Democritus
all matter can be divided into smaller and smaller pieces until a single indivisible particle was reached
Aristotle
everything is made up of earth air water and fire
John Dalton
each atom is a simple sphere with nothing else internally
J.J. Tomson
Atoms as a whole are neutral but negative electrons are scattered throughout it
There must be something positive in the atom for it to be neutral
Ernest Rutherford
Most of the atom is empty space where negative electrons move in
There is a small dense ball in the center, called the nucleus
The nucleus is positively charged, containing protons
James Chadwick
uncharged/neutral particles in the nucleus called neutrons
Niels Bohr
each electron have specific amounts of energy (electron shells)
Periods and groups on the periodic table
Periods are rows that go horizontally
A group/family are columns that go vertically
Groups on the periodic table
Group 1 under hydrogen: Alkali metals
Soft, high luster, highly reactive with other elements usually halogens
Group 2: Alkaline earth metals
Reacts often with oxygen, bright when burning
Group 3 to 12: Transition metals
All similar to each other
Group 17: Halogens
Highly reactive usually with alkali metals, solid liquid or gas at room temp,
Group 18: Noble gases
All gas, no reactions, colourless, odourless, tasteless
Hydrogen
Doesn’t fit into any of the other categories, similar to alkali metals but isn't a gas
Isotopes
Atoms of the same element have the same number of protons but varying # of neutrons
Ions
gained or lost electrons
Cations: lost electrons, usually metals (+1)
Anions: gain electrons, usually non-metals (-1)
Oxygen gas test
glowing splint (not lit) above a test tube relights with oxygen
Carbon dioxide gas test
extinguishes lit/burning splint with a squeaky pop OR bubble it through lime water → turns milky
Hydrogen gas test
extinguishes lit/burning splint with a squeaky pop, it’s flammable therefore → combustion
difference between an ionic bond and a molecular bond
Ionic Bond: when a metal comes into contact with a non-metal, they create an ionic bond (attraction between cations and anions), resulting in an ionic compound
Molecular Bond: 2 non-metals come together and share an electron, making covalent bonds which can turn into molecular compounds or molecular elements
difference between molecular elements and molecular compounds
Molecular elements: 2 atoms of 1 element
7 of these elements (diatomic): BrINClHOF
Bromine, Iodine, Nitrogen, Chlorine, Hydrogen, Oxygen, Fluorine
Molecular compounds: 2+ different elements
Chemical formulas show what elements are present
E.g. h2o, the 2 shows there are 2 hydrogen atoms
How Atoms Combine
Metals and metals
Alloys: created by melting two or more metals and mixing them together while still in liquid form, only homogeneous mixtures that aren’t transparent
Metals and non-metals
Name the metal first and the non-metal second
Keep the root of the non-metal and add an “-ide” at the end
Non-metals and nonmetals
They share an electron, the positive charge of both nucleus attract the electron
Covalent bond
Naming Molecular Compounds
mon(o) - only applies for the second element
di - 2
tri - 3
tetra - 4
penta - 5
…hexa…hepta
Names and Formulas of Ionic Compounds
Zero-sum rule: the sum in all charges must equal zero
Univalent metal: creates only 1 type of charge
Multivalent metal: can form more than 1 type of ion; e.g. copper can be 1+ or 2+
They will always include a roman numeral to indicate which type it is
E.g. copper(l) and copper(ll)
Standard Atomic Notation
Element symbol is located in the middle
Atomic number is on the bottom left (# of protons or # on the periodic table)
Mass number is on the top left (protons + neutrons)
Charge is on the top right (positive, negative, neutral)
Atomic structure
The number of protons in the nucleus determines what the element number is (atomic number) of the element
Atom: p+ = e–
Ion: p+ ≠ e–
Mass #: p+ + n0