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potassium (K)
highly soluble macronutrient that doesn’t precipitate, mobile, used in gradients, catalysts, hydraulic gradients
K accessibility in soil
only 1% is found in soil solution, of that 2% is available to plants
adsorbed forms of K
exchangeable (K+ on CEC sites of clay and OM), non-exchangeable (fixed inside clay minerals and resistant to weathering)
% base saturation
the extent to which the absorption complex of a soil is saturated with base forming cations (not Al or H)
egg carton effect
clay has spaces between layers that match the size of K, traps K and only NH4+ can displace cations
luxury consumption
Plants take up K as much as they can even if its not needed, which displaces other cations (Mg, Ca). Leads to deficiencies in other cations with lower affinities
K deficiency symptoms
In older leaves, chlorosis and necrosis on leaf edge, white necrotic spots, plants fall over
problems with K in the environment
Excess K on exchange sites lead to luxury consumption. Milk fever from Ca displacement causes low clotting and livestock can bleed to death, Grass tetany due to Mg displacement causes death, convulsions, and pedaling motion
What environmental variables effect K?
Low O2 levels decrease K uptake, low soil moisture increases K fixation (needs to move in soil solution), high rainfall/irrigation leaches K
When is the best time to apply K?
Apply around rooting/germination, annually in the spring
Extraction Theory
Extract K from clay by exchanging it with NH4+, 90% is extracted which is a source of error, analyze using flame photometry
saline soils