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Change in momentum of molecule colliding with walls of container is Δp =
Momentum before = mu
Momentum after = -mu
change in momentum = 2mu
Time taken between successive collisions of molecule with wall is t =
Distance/speed = 2L/u
Frequency of collisions with wall is f =
u/2L
Average force on (from) 1 molecule is F (1 molecule) =
2mu x u/2L = mu2/L
Average force on (from) N molecules is F =
Pressure on wall is p =
For one molecule, with velocity components u, v and w, square speed is c2 =
u2 + v2+ w2
So finally
pV = 1/3 Nm(average c)2