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Relationship between pH and pOH
H + pOH = 14
pascal
newton/m^2
newton
kg•m/s2
degree of carbon
number of carbon atoms bonded to it
acute toxicity
adverse effect due to a single dose of a contaminant
chronic toxicity
adverse effects resulting from repeated doses of or long-term exposure to a substance
mutagenic
ability to induce mutations in genes or chromosomes of an organism
teratogenic
ability to develop defects in embyro
process of risk assessment
1. data collection and evaluation 2. toxicity assessment 3. exposure assessment 4. risk characterization or toxicity assessment 5. risk management
TLV
Threshold Limit Value
Frank effect
marks the point where maximum effects are observed with little increase in effect for increasing dosing
TLV-TWA
maximum time-weighted average concentration that all workers may be exposed to during an 8 hour day and 40 hour week. For inhalation route of exposure.
LD50
mg/kg body mass at which 50% of the test animals died
law of additive effects
applies only when the effects from the component gases and vapors occur within the same organs
reference dose
a metric for non-carcinogenic effects, and is the dose that a healthy person can be exposed to daily without adverse effects
internal dose
crosses one of the route barriers into the body
density
mass per volume
specific volume
volume per mass
specific weight
weight per unit volume
specific gravity
dimensionless ratio of a fluids density to a standard reference density. for solids and liquids the reference is pure water
absolute pressures
pressures measured with respect to atmospheric pressure
stress
force per unit area
viscosity
a fluids resistance to flow
hydrostatic pressure
pressure a fluid exerts on an immersed object or container walls
a stationary, incompressible fluid behaves according to the following characteristics
function of vertical depth (and density) only
pressure varies linearly with vertical depth
pressure is independent of an objects area and size and of the mass of water above the objectThese characteristics describe hydrostatic pressure.
pressure at a point has the same magnitude in every direction
surface energy
work done per unit area to create a new surface in the material
internal atoms
bonded to 6 other atoms so need to spend a lot of energy to break all the bonds
external atoms
compared to external who is bonded to 4 or 2 atoms
magnetically hard
retain magnetization well
magnetically soft
lose magnetization easily
bond length
distance between two nuclei at the point of minimum energy
covalent bond
sharing electrons
electronegativity
ability of an atom to attract shared electronspola
polarity
separation of chargespolar
polar covalent bond
covalent bond where two atoms have different electronegativities causing separation of chargesi
ionic bond
bond formed by transfer of electrons from one atom to another (metal to nonmetal)ion
ionic compounds
crystalline, soluble in water, conduct electricityc
covalent compounds
softer solids, liquids, gases, not soluble in watermet
metallic bonds
group of metal atoms share a cloud of valence electrons (delocalize e-)
oxidation state
the hypothetical charge that an atom would have if all valence electrons were transferred
type of reaction oxidation is
anode reaction
water pressure range for domestic water supply
40-80psig
ductility
allows a body to undergo plastic deformation before failure (fractures at large strains). Allows a material to be drawn longitudinally to a reduced section under tensile force
description of ductile material
high degree of plasticity and strength
post elastic strain >5%
ductile (examples, lead, plastic, mild steel, copper)
brittleness
property of a material, by which a material fails abruptly w/o undergoing plastic deformation. implies that it cannot be strung out.
wetted perimeter
length of the line tracing the interface between the fluid and channel
compressible fluid
density is not constant
incompressible fluid
density is constant
Pressure drop in orifice meter when there is no change in height (p1-p2)
rho(hg)*g*deltah
specific weight of a liquid (gamma)
density gravity (rho g)
Tau
shear stress (pa)
laminar flow
shear stress distribution is linear, low reynolds number
turbulent flow
high reynolds number
a submerged body will be stable if the center of buoyancy
is directly above the center of gravity
what change occurs in the energy grade line when an ideal fluid is replaced with water in a pipe system?
the EGl acquires a downward slope
Buoyant force equation
Fb=rho*area*g*h
circumference of a sphere
2*pi*R
high oxidation levels means
more susceptible to corrosion (atoms will lose electrons and form positive ions to make water)
daily per capita flow of water includes
all domestic, commercial, industrial, and public uses and is about (160-165 gpcd)
gpcd
gallons per capita day
when compared to extraction wells pumping at the same rate from the same function, what is the desired screen length for injection wells?
twice the extraction well screen length
purpose of adding gypsum to soil
increase concentration of calcium
soils with higher ph usually have
higher sodium adsorption ratio
optimized biological nitrification is between what pH
7.5 and 8
plants like what biological nitrification pH
7.0-7.2
thermodynamics
study of a substances energy related properties
saturated liquid
liquid that has absorbed as much heat energy as it can without vaporizing
subcooled liquid
liquid that is not saturated
saturated vapor
a vapor that is on the verge of condensing
enthalpy
total useful energy of a substance
entropy
measure of the energy that is no longer available to perform useful work within the current environment
What conditions are the smallest deviations from the ideal gas law?
high temps and low pressures. This is because the distance between the molecules is large so the interactions are minimal
Entropy, S
energy that is no longer available to perform useful work
enthalpy, h
total useful energy of a substance
internal energy, u
a measure of translational, rotational, and vibrational kinetic energies of molecules
what happens when a liquid’s vapor pressure = surrounding pressure?
the liquid boils
pure substance
properties are uniform throughoutcr
critical temperature
properties of gas can’t be distinguished from liquids. liquids cant exist beyond this temperature
isentropic
entropy is constant, no energy crosses system boundaries, reversible
heat flow, Q, equals to
specific enthalpy (h)
adiabatic
no energy crosses the system boundary, includes isentropic and throttling processes
throttling process
adiabatic process where there is no change in enthalpy, significant pressure drop
isobaric process
constant pressure process
isothermal process
constant temperature processing
isochoric or isometric process
constant volume process
Heat, Q in thermo
positive if heat flows into system
W, work in thermo done on system is negative or positive?
positive if does work on surroundings
Changes in enthalpy (H), entropy (s), and internal energy (U)
positive of increased within system
in thermodynamics, if the flow is steady then
mass-flow terms are equal
C
specific heat
Cp
change in enthalpy/change in temperature
ideal rankine cycle
two constant pressure and two isentropic processes
second law of thermodynamics
natural tendency of any isolated system to degenerate into a more disordered state, energy is transferred or transformed
area in the carnot cycle diagram
heat
water level of a well drilled into an artesian acquifer
above the level of the top of the water in the aquifer
point where soil becomes saturated with water
water volume/void volume = 1
CaCo3 Equivalents
Cas substance = (EW CaCO3) / EWsubstance
hardness
calcium + magnesium (as equivalents of CaCO3), polyvalent metallic cations
recarbonation after softening is to
lower its pH and reduce scale forming potential