OChem Unit 3

Br2 / AlBr3

Cl2 / AlCl3

I2 / CuCl2

fuming H2SO4

HNO3 / H2SO4

CH3Cl / AlCl3 (rearrangements possible)

acyl group: Cl-C=O-CH-(CH3)2

Clemmensen reduction: Zn(Hg)

reduction: 1) Zn, HCl 2) NaOH

xs. NBS

1. KMnO4, H2O, heat

2. H3O+

[H+], H2O

[H+],ROH, -H2O

[H+], RO-CH2-CH2-OR, -H2O

[H+], HS-CH2-CH2-SH, -H2O

H2NNH2, [H+], -H2O

R2NH, [H+], -H2O

RNH2, [H+], -H2O

NH2OH, [H+], -H2O

1. LAH

2. H3O+

1. RMgBr

2. H3O+

Ph3P=CH2

RCO3H

KCN, HCl

1. NaNH2, NH3 (liq.)

2. H3O+