Chemistry - Chapter 28: Transition elements

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Transition element

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11 Terms

1

Transition element

A block d element which forms one or more stable ions with incomplete d orbitals

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2

Ligand

A molecule/ion with one/more lone pairs of electrons which form dative covalent bonds to a central transition element atom/ion

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3

Complex ion

A central transmission metal/ion surround by ligands, bonded to the central ion by dative covalent bond

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4

Co-ordination number

The number of co-ordinate bonds formed by ligands

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5

Monodentate

Ligand forming 1 co-ordinate bond with a transition element ion, using 1 lone pair of electron

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6

Bidentate

Ligand forming 2 co-ordinate bond with a transition element ion, using 2 lone pairs of electrons

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7

Ligand exchange

Ligands can be exchanged, wholly or partially for other ligands.

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8

Condition for ligand exchange

New complex formed is more stable than the original complex

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9

Degenerate orbitals

Atomic orbitals in the same energy level in a given subshell

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10

Non-degenerate orbitals

Atomic orbitals in the same sub-shell that has slightly different amount of energy

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11

Stability constant

Equilibrium constant for the formation of a complex ion in a solvent from its constituent ions or molecules

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