Modern Atomic Theory Test

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29 Terms

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Excited State

An atom is in an excited state when it possesses more energy than in its ground state.

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Ground State

An atom is in its ground state when it is in its lowest possible energy state.

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Photon

A discrete quantity of electromagnetic radiation. (a packet of energy)

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Orbital

A region in space where there is a 90% probability of finding an electron.

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s subshell capacity

A particular s-subshell can hold a maximum of 2 electrons.

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p subshell capacity

A p subshell consists of three orbitals and can hold a maximum of 6 electrons.

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p orbital capacity

A specific p orbital can hold a maximum of 2 electrons of opposite spin.

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Valence Electrons

The electrons in the outermost shell of an atom.

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Core Electrons

Electrons in principal energy levels closer to the nucleus than the outermost shell.

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Periodic Table Arrangement

The periodic table is arranged based on the electronic structure of the atoms.

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Electron Configuration of Na

1s² 2s² 2p⁶ 3s¹.

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Electron Configuration of N

1s² 2s² 2p³.

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Electron Configuration of Be

1s² 2s².

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Electron Configuration of Sr

1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰ 4p⁶ 5s² or [Kr] 5s².

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Ionization Energy

The energy required to remove an electron from an atom.

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Atomic Radius

The distance from the center of the nucleus to the outer edge of the valence electrons.

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Ionization Energy Trend in Groups

Ionization energies decrease from top to bottom in a vertical group.

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Atomic Size Trend in Groups

Atomic radius increases from top to bottom in a vertical group.

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Ionization Energy Trend in Periods

Atomic sizes decrease across a horizontal row of the periodic table.

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Atom's return to ground state

An excited atom returns to its ground state by emitting excess energy as electromagnetic radiation.

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Photon Energy and Wavelength Relation

Longer wavelength photons carry less energy than shorter wavelength photons.

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Wave Mechanical Orbitals vs. Bohr’s Orbits

Wave-mechanical orbitals predict probabilities of finding electrons rather than specific paths.

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Unpaired Electrons in p Orbitals

Unpaired electrons are placed in separate p orbitals to minimize interelectronic repulsion.

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Electrons in Principal Energy Levels

The first principal level can hold 2 electrons; the second can hold a maximum of 8 electrons.

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Valence Electrons Importance

Valence electrons affect an atom's chemical properties and are related to the atom's position on the periodic table.

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Excited States Emission of Radiation

Excited atoms emit only discrete photons of characteristic wavelength and energy.

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Trend Explanation for Atomic Radius

Atomic radius decreases across periods due to increased nuclear charge, while it increases down groups due to additional energy levels.

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Shorthand Electron Configuration

Core electrons are represented by the closest noble gas, conveying only the valence electrons and their orbitals.

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Energy Level, Sublevel, and Orbital Definition

Energy levels are discrete states, sublevels are divisions within energy levels, and orbitals are probable locations of electrons.