Ch 18 - Rxns of Aldehydes and Ketones
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Last updated 1:00 AM on 3/6/25
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4 Terms
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aldehyde/ketone + HCN (or -CN; H+)
cyanohydrin formation
CN and OH on same carbon
2
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nitrile + H2/Pd
reduction of CN pi bonds
C triple bond to N goes to CNH2
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nitrile + H2O/H+/heat
converted to carboxylic acid
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aldehyde/ketone + H2O/H+
hydrate formation
OH and OH on same carbon
water favors carbonyl form except for small aldehydes
halogenated aldehydes/ketones form hydrates in product favored rxns
Note 
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