Ch 18 - Rxns of Aldehydes and Ketones

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4 Terms

1

aldehyde/ketone + HCN (or -CN; H+)

cyanohydrin formation

  • CN and OH on same carbon

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2

nitrile + H2/Pd

reduction of CN pi bonds

  • C triple bond to N goes to CNH2

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3

nitrile + H2O/H+/heat

converted to carboxylic acid

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4

aldehyde/ketone + H2O/H+

hydrate formation

  • OH and OH on same carbon

  • water favors carbonyl form except for small aldehydes

  • halogenated aldehydes/ketones form hydrates in product favored rxns

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