8. Oxidation and reduction of organic compounds

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30 Terms

1
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How do alcohols react with oxidizing agents?

They undergo selective oxidation at the carbon attached to the –OH group while maintaining the carbon skeleton.

2
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What is a common oxidizing agent for alcohols?

Acidified potassium dichromate (K₂Cr₂O₇), which changes from orange (Cr(VI)) to green (Cr(III)).

3
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What are the oxidation products of primary alcohols?

They oxidize first to aldehydes and then to carboxylic acids if excess oxidizing agent is used.

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What is the oxidation product of secondary alcohols?

They oxidize to ketones.

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Can tertiary alcohols be oxidized using K₂Cr₂O₇? Why or why not?

No, because they lack a hydrogen atom on the carbon bonded to the hydroxyl group.

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What is reflux, and when is it used?

Reflux is a technique where vapors condense and return to the reaction mixture; used for oxidizing primary alcohols to carboxylic acids or secondary alcohols to ketones.

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What is distillation, and when is it used?

Distillation separates a volatile product from a reaction mixture; used to isolate aldehydes before further oxidation.

8
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Why does wine left in the air smell like vinegar?

Bacteria oxidize ethanol to ethanoic acid (acetic acid).

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What is the reducing agent used to reduce organic compounds?

  • Lithium aluminum hydride (LiAlHâ‚„) or sodium borohydride (NaBHâ‚„).

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How can carboxylic acids be reduced?

In a two-step reaction via an aldehyde intermediate, forming a primary alcohol.

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How can ketones be reduced?

Ketones reduce to secondary alcohols using reducing agents like LiAlHâ‚„ or NaBHâ‚„.

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What is the general reaction for reducing alkenes and alkynes?

Hydrogenation, where hydrogen gas adds to multiple bonds in the presence of a metal catalyst.

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What catalysts are used for hydrogenation?

  • Nickel (Ni), platinum (Pt), or palladium (Pd).

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How does reduction affect the degree of unsaturation in organic compounds?

It decreases unsaturation by converting double or triple bonds into single bonds.

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What happens when excess hydrogen reacts with an alkyne?

The alkyne is reduced to an alkane.

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What is the product when propene reacts with hydrogen gas?

Propane.

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What is the product when pent-1-yne reacts with excess hydrogen gas?

Pentane.

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Oxidation

A reaction where a molecule gains oxygen or loses hydrogen.

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Reduction

A reaction where a molecule gains hydrogen or loses oxygen.

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Oxidizing Agent

A substance that causes oxidation by accepting electrons (e.g., K₂Cr₂O₇).

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Reducing Agent

A substance that causes reduction by donating electrons (e.g., LiAlHâ‚„, NaBHâ‚„).

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Primary Alcohols

Alcohols where the –OH group is attached to a carbon bonded to one other carbon.

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Secondary Alcohols

Alcohols where the –OH group is attached to a carbon bonded to two other carbons.

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Tertiary Alcohols

Alcohols where the –OH group is attached to a carbon bonded to three other carbons.

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Aldehyde

  • A compound with a carbonyl group (C=O) at the end of a carbon chain.

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Ketone

A compound with a carbonyl group (C=O) within a carbon chain.

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Carboxylic Acid

compound with a carboxyl group (-COOH).

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Hydrogenation

  • A reduction reaction where hydrogen gas is added to unsaturated compounds.

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Alkyne to Alkane Conversion

The reaction where an alkyne is completely reduced to an alkane using excess hydrogen gas.

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