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what determines the properties of elements in periodic trends
valence electrons
what is the first concept that explains periodic trends
opposite charges attract: the positively charged nucleus attracts electrons to itself. This fundamental attraction influences atomic size, ionization energy, and electronegativity.
what is the second concept that explains periodic trends
like charges repel: electrons repel each other and organize themselves to minimize said repulsion. includes afbaus rule, hunds rule, and pauli exclusion principle
what is the third concept that explains periodic trends
more energy levels results in more sheilding
what is shielding
the blocking of nuclear charge (charge of nucleus) from reaching and attracting the valence electron and shell due to more energy levels
what is atomic radii
distance from nucleus to outermost electron
what happens to the atomic radii as you go across a period
the atomic radii decreases
why does atomic radii decrease as you go across a period
increased nuclear charge pulls valence electrons closer to the nucleus, reducing atomic radii
what happens to the atomic radii as you go down a group
it increases
why does the atomic radii increase as you move down a group
because as you move down a group the outermost orbitals size increases, shielding valence electrons from nucleuses pull, and overpowering the increased pull of the positive nucleus on valence electrons, so atomic radii increases
does more protons make atom smaller or bigger
smaller because it pulls the electrons in better
what does isoelectric mean
if the atoms we are comparing have the same number of electrons and configuration
which has a greater effect: shielding or nuclear charge
more shielding has a greater effect than more nuclear charge
what are cations
positive ions formed by losing electrons
are cations bigger or smaller than their atoms
smaller because they have the same nuclear charge but less electrons to pull in and less energy levels
what are anions
negative ions, formed by gaining electrons with ide endings (nonmetals)
are anions bigger or smaller than their atoms
the atom is smaller than the anion because they have the same nuclear charge but less electrons to pull in
what are the 3 most stable orientations in order
1) p^6 filled
2) filled sublevel
3) a half filled sublevel
what is ionization energy
the energy required to remove an electron from an atom in its gaseous state
what does ionization energy dictate
how strongly atoms nucleus hold onto valence electrons
what does a high ionization energy result in
atom has a strong hold on the electrons, making it hard to remove them and requiring more energy
what does a low ionization energy result in
atom has a weak hold on electrons, making it easy to remove them and requiring less energy
what happens to ionization energy as you go across a period
it increases, but the shielding stays consistent whilst atoms get smaller
why does ionization energy increase as you go across a period
because increased nuclear charge of each successive element makes increased hold on valence electrons (since stronger NC=harder to remove valence electrons as electrons pulled closer to positive nucleus)
what happens to ionization energy as you move down a group
it decreases
why does ionization energy decrease as you move down a group
because the increasing atomic size pushes valence electrons away from the nucleus, so it takes less energy to remove the electron since strength of attraction is less
what is successive ionization energy
removal of the 2nd, 3rd, 4th, etc. electrons from a species
what happens to the successive ionization energy as you move across a period
you need more energy for each one, the amount needed increases because the increase of positive charge binds electrons stronger
when does the energy jump occur
when core electrons are being removed instead of valence electrons because it takes more energy to break up stable electrons
why do cations get smaller and smaller the more electrons you lose
more nuclear charge, less electrons means it pulls them in better
what is electronegativity
ability of an atom in a molecule to attract shared electrons when forming a chemical bond
what happens to electronegativity when you go across periods
increases because increasing nuclear charge as protons increase also increase electron attracting power
what happens to electronegativity as you go down a group
it decreases because of shielding. the electrons in lower energy levels shield the positive charge of the nucleus from outer electrons, decreasing electron attracting power and outer electrons wotn be tightly bound to the atom
which types of elements dont have electronegaitvity
noble gases bc full shell and stable so they dont want to attract eelctrons when bonding