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Hess’s law
The total enthalpy change of a reaction is always the same, no matter which route is taken.
what is working out the theoretical lattice enthalpy
doing calculations based on the purely ionic model of a lattice.
What does the purely ionic model of a lattice assume?
Assumes that all the ions are spherical, and have their charge evenly districuted among them.
List the order of enthalpies in the Born-Haber cycle:
Down to Up
Enthalpy of formation
Enthalpy of atomisation
Ionisation energy (for positive ion)
Down, Electron affinity of negative ion
Down, Lattice enthalpy of formation of ionic compound