Alkene and Alkyne Reaction Conditions

Alkene Ozonolysis

O3 / DMS

Alkyne Ozonolysis

O3 / H2O

Hydrohalogenation (Markovnikov)

HCl, HBr

Hydrohalogenation (Anti-Markovnikov)

HBr / ROOR

Acid Catalyzed Hydration

H2SO4 / H2O

Oxymercuration - Demercuration

1) Hg (oAc)2, H2O 2) NaBH4

Hydroboration Oxidation (Anti-Markovnikov)

1) NaBH4 , THF / 2) H2O2, NaOH

Catalytic Hydrogenation (Syn)

H2 / Pt

Halogenation (Anti)

Cl2

Halihydration (Anti)

Cl2 / H2O

Epoxidation Anti Dihydroxilation

1) mCPBA / 2) H3O

Syn Dihydroxylation

1) Cold KMnO4 / 2) NaOH, H2O

Hydrogenation of Alkynes

H2 / Pd

Lindlar’s Catalyst

Lindlars / H2

Metal Ammonia Reduction

Na or Li / NH3

Acid Catalyzed Hydration of Alkynes

H2SO4 / H2O

Oxymercuration - Demercuration of Alkynes

HgSO4 / H2O

Hydroboration of Alkynes

1) R2BH 2) NaOH, H2O2

Allylic Radical Halogenation

NBS