redox reagents
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Last updated 11:00 AM on 2/11/26
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10 Terms
1
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H2, Pd-C
alkyne/alkene —> alkane (syn)
2
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Na, NH3
alkyne —> alkene (trans)
3
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H2, Lindlar catalyst
alkyne —> alkene (syn)
4
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LiAlH4 or NaBH4
carbonyl —> OH
5
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mCPBA
1) alkene —> epoxide (achiral —> achiral/racemic mixture)
2) epoxide —> 2 OH groups (anti)
6
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OsO4/NMO
2 OH groups added to alkene (syn)
7
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1) O3
2) DMS or Zn
cleavage, two groups w C=O
8
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PCC
primary alcohol —> aldehyde (in presence of water, undergoes further oxidation)
9
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CrO3 and Na2Cr2O7
primary alcohol —> carboxylic acid
10
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Na2Cr2O7
(PCC or CrO3 possibly)
secondary alcohol —> ketone (C=O)
Note 
Flashcards (24)