C1.3 Chemical Calculations (copy)

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22 Terms

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Relative atomic mass

 is the weighted mean mass of an atom of an element compared to 1/12th of a carbon-12 atom.

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Relative isotopic mass

is the mass of an atom of an isotope of the element compared to 1/12th of a carbon-12 atom

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Stage 1 of a mass spectrometer

vapourisation

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Stage 2 of a mass spectrometer

ionisation

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Stage 3 of a mass spectrometer

acceleration

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Stage 4 of a mass spectrometer

deflection

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Stage 5 of a mass spectrometer

detection

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Empirical formula

the simplest ratio of atoms in a compound

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Molecular formula

the actual number and types of atom in a molecule

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n = (solids/liquids)

m/Mr

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n = (solutions)

Concentration x Volume

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n = (gases)

Volume/molar volume

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Ideal gas equation

PV = nRT

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Units of V in ideal gas equation

metres cubed (m3)

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Units of temperature in ideal gas equation

Kelvin (K)

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Units of pressure in ideal gas equation

Pascals (Pa)

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Molar volume at rtp

24dm3

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Molar volume at stp

22.4dm3

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Atom economy =

mass of useful product / total mass of reactants

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Percentage yield =

actual yield / theoretical yield x 100

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Avogadro’s Number =

6.02 x 1023 particles/mol

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Percentage uncertainty in a measurement =

((error per measurement x number of measurements)/value) x 100