synthetic transformations & reagents

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83 Terms

1
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) Hg(OAc)2, H2O, THF 2) NaBH4

2
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) Hg(OAc)2, HOR, THF 2) NaBH4

3
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) BH3, THF 2) H2O2, NaOH, H2O

4
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

HBr, peroxides (ROOR), heat or light

5
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

HX, cold, dark, no peroxides

6
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

Br2

7
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

MCPBA

8
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) strong base 2) dilute acid

9
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

H+, HOR

10
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

Br2, HOR

11
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

CHCl3, KOH

12
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

CH2I2, Zn(Cu)

13
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) BH3, THF 2) H2O2, NaOH, H2O

14
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

H2, Pt or Pd

15
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

H2, Pt or Pd

16
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

H2, Ni2B or H2, Lindlar Catalyst

17
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

Na, NH3 (l)

18
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

PCC

19
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

KMnO4 or Na2Cr2O7, acid, water or CrO3/pyridine, acid, water or PCC

20
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

KMnO4 or Na2Cr2O7, acid, water or CrO3, acid, water

21
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) OsO4 2) H2O2 or NaHSO3

22
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) O3 2) Zn, HOAc

23
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) KMnO4 (hot) 2) H3O+, H2O

24
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) HX, dark, cold, no peroxides 2) HX, dark, cold, no peroxides

25
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) X2 2) X2

26
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

H2O, H2SO4, HgSO4

27
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) BH3, THF 2) H2O2, NaOH, H2O

28
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

NaNH2

29
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

H2O, H2SO4

30
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

HX

31
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<p>list the <strong>best </strong>reagents that will give this product</p>

list the best reagents that will give this product

SOCl2

32
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<p>list the <strong>best </strong>reagents that will give this product</p>

list the best reagents that will give this product

PBr3

33
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

NaOH or KOH

34
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

NaOR

35
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

weak base, ethanol (or other polar protic solvent), heat

36
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

acid (usually H2SO4 or H3PO4), heat

37
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

small base

38
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

large base

39
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

Cl2, light

40
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

Br2, light

41
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

radical initiator, Br2 (e.g. NBS/heat or Br2/light)

42
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

Br2, cold, dark, no peroxides

43
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

radical initiator, HBr

44
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

HBr, cold, dark, no peroxides

45
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

Mg metal, diethyl ether

46
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

2 Li metal, diethyl ether

47
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

HOR or HOH

48
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) Li or Mg metal, diethyl ether 2) D2O

49
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) R3C-Z (Z = Li or MgX), diethyl ether 2) H3O+, H2O (dilute acid)

50
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) R3C-Z (Z = Li or MgX), diethyl ether 2) R’’CH2X

51
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) LiAlH4 or NaBH4 2) H3O+, H2O (dilute acid)

52
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) Li metal 2) CuI

53
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<p>list the reagents that will give this product </p>

list the reagents that will give this product

any deuterated strong acid

54
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<p>list the reagents that will give this product </p>

list the reagents that will give this product

H2SO4, HNO3

55
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<p>list the reagents that will give this product </p>

list the reagents that will give this product

anhydrous sulfuric acid (H2SO4, no water)

56
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<p>list the reagents that will give this product </p>

list the reagents that will give this product

Br2, FeBr3 or Cl2, FeCl3

57
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<p>list the reagents that will give this product </p>

list the reagents that will give this product

RX, AlX3 (X = Cl or Br)

58
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<p>list the reagents that will give this product </p>

list the reagents that will give this product

XRC=O, AlX3 (X = Cl or Br)

59
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

Zn(Hg), HCl

60
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

H2, Pd

61
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

H2O, H3O+

62
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

HCN, CN-

63
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

Nuc-, HNuc

64
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

SOCl2 or PBr3

65
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

R’NH2, H+

66
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

R2’NH, H+

67
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) R’OH, H+ 2) R’OH, H+

68
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

H+

69
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) NaH 2) R’X

70
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) Nuc- (NOT grignards, lithium reagents, and RCC-) 2) H+

71
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

H+, R2NH

72
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

H2NNH2, KOH

73
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) PPh3, butyllithium 2) R2CO

74
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) LiAlH4 or NaBH4 2) H3O+

75
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) LiAlH4 or NaBH4 2) H3O+

76
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) LiAlH4 2) H3O+

77
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

R’OH (excess), H+

78
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

H2O (excess), H+

79
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) KOH 2) H+

80
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

H+ or R’’ONa

81
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

H+ or 1) -OH 2) neutralize

82
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) CO2 2) neutralize

83
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<p>list the reagents that will give this product</p>

list the reagents that will give this product

1) R’MgBr 2) H+, H2O