Chapter 13 - Reaction Orgo

Reduction with sodium in Liquid ammonia

Starts with triiple bond

Uses Na, NH3, and H2O

Ends with double bond no different substituents seen in product

Hydrohalogenation of Alkynes

Starts with triple bond

Uses HBr (excess) or X, or includes bezne to add extra bond

Ends with Two Br or X on the same carbon same side single bonded (cis)

Double halogenation of an alkyne

Starts with triple bond

Uses Cl2 or X2, LiCl or LiX, and AcOH

Uses Br (excess) or X, with CCl4 when has hook not a straight line

Ends with double bond with Cl or X on two carbons beside each other on different side (trans)

Hydroboration -Oxidation

Starts with triple bond

Uses BH3, THF, H2O2, NaOH, H2O

Oxygen with double bonds gets added where triple bond ends

Meruric Ion

Strats with triple bond

Uses H2SO4, HgSO4, and H2O

ENds with an oxygen pn the secnd carbon of the product (total four)

Alkylation of a terminal alkyne (connected to hydrogens)

Startes with triple bonds

Uses NaH, CH3I, Et2O

Ends with a methyl gorups at the end of the truiple bond

Double Dehydrohalogenation

Startes with single two Br or X on different carbonc (trans) beside each other

Uses NaNH2 excess

Ends with no Br or X and wiht a triple bond

Alkylation with carbonyl compounds

Startes with tripple bond

Uses EtMgBr: CH3CHO, H, H2O

Ends iwth a OH and methyl at the end of the triple bond

Hydrogenation with Lindlar’s catalyst

Starts wth triple bond with CH3 at the end

Uses H2, and Lindalr’s catlayst

ends with a double bond and Both substituents facing the sam eway (cis)

Hydrogenation with Pt, PD-C, and Ra-Ni

Startes with triple bond

uses H2, PD-C, and Et2O

End with single bond and CH3 attahced ot the end of it ( triple bond)

Radical addtition with Anti-Marlovlv

Startes with triple bond

Uses HBr or X, with ROOR

Ends with a double bond and Br or X attached to it

Heck reaction

Ring is open (hexane)

Uses Pd(OAc)2, Ph3P, and heat

Ends with the ring closed (pentane) with leaving gorup gone

Suzuki

Ring is open

Uses Pd(Ph3P)4, Ph3P, NaHCO3, and H2O

Ends with ring close and no substients

Hydration / haloghydrin

Starts with triple bond

Use Br2 or X2, with H2O

Ends with both OH and Br or X on opposite sides on diffrent carons with Oxygen with a double bond