Fragmentation and Common Alkyl Ions Mass Spec

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10 Terms

1
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M-15

ºCH3

2
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M-29

ºCH2CH3 [M-(15+14)] ethyl

3
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M-43

ºCH2CH2CH3 [M-(29+14)] propyl

4
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M-57

ºCH2CH2CH2CH3 (IM-(43+14)] butyl

5
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M-71

'CH2CH2CH2СН2СНз [M-(57+14)] pentyl

6
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M-85

CH2CH2CH-CH2CH2CH3 [M-(71+14)] hexyl

7
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M-99

CH2CH2CH2CH2CH2CH2CH3 [M-(85+14)] heptyl

8
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M-1

usually small

suggests alcohol

9
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M-18

suggests alcohol (loss of water)

10
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M-31

primary alcohol

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