Quantum Mechanics

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12 Terms

1
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Despite being a noble gas, why is Radon easy to ionize?

very large atom, almost no hold on outer electrons

2
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What are the three principles used when constructing atomic energy diagrams?

Aufbau principle, Paulis exclusion principle, and Hunds rule

3
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What is Aufbau’s principle?

electrons are placed in lowest unoccupied energy level/orbital

4
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What is Hund’s Rule?

Degenerate (same energy) orbital get one electron before you are allowed

to fill any one completely

5
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What is Paulis exclusion principle?

each orbital/orientation can hold a max of two electrons

6
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Explain the octet rule

elements are most sable with a full set or complete orbital diagram

7
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What are the three exceptions to the octet rule

  1. Boron and hydrogen are happy with less than 8

  2. Period 2 and beyond/hypervalent are happy with more than 8

  3. free radicals

8
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What does it mean when a set of orbitals undergo hybridization?

When distinct sets of orbitals within the same period mix to form a new set of degenerate orbitals

9
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Why can sulfur obtain hypervalent states where oxygen cant

Sulfur has access to the phantom 2d orbital which allows its orbitals to undergo a greater hybridization, meaning that one or both lone pairs can be turned into bonding electrons

10
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What is planck’s constant?

6.626×10-34 J/s

11
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What is the speed of light

3.0 × 10^8

12
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How many Joules is an electron volt equal to?

1.602x10-19 J = 1 eV