Oxidizers and Reducers

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7 Terms

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PCC

Primary OH to aldehyde, secondary OH to ketone.

2
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Na2Cr2O7 / H2SO4

Strong oxidizer. Primary OH —> Carboxylic Acid. Secondary OH —> Ketone

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NaOCl (Bleach)

Primary OH —> Aldehyde Secondary OH —> Ketones

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NaBH4

Reduces aldehydes and ketones to alcohol reliably.

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LAH

Strong reducer. Reduces carboxylic acids, ketones, aldehydes, and most groups. Fully reduces molecule

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DIBAL-H (-78)

Reduces esters to aldehydes

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LiAlH(Ot-Bu)3

Turns acid chlorides into aldehydes.