uwsp chem 105 midterm review

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52 Terms

1
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From quiz 3 Q. 5: how many carbon atoms are in the phenylalanine structure?

9

2
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Quiz 3 Q. 6: which of the following functional groups is present in the phenylalanine structure?

carboxylic acid

3
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the polyatomic ion C(NH2)3^+

24

4
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The ions Ca^2+ and PO4^-3 form an ionic compound with the formula

Ca3(PO4)2

5
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_________ bonds are formed by sharing electrons, while _________ bonds are formed by electrostatic attraction between ions

covalent, ionic

6
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Quiz 3 Q. 7: how many lone pairs of electrons are present around the circled N atom?

1

7
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which of the following compounds would you expect to contain ionic bonds?

CaO

8
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based on the octet rule, magnesium will form the _______ ion

Mg^2+

9
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the correct name for N2O5 is

dinitrogen pentoxide

10
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what is the empirical formula for C8H16O4

C2H4O

11
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Quiz 3 Q. 14: what is the formal charge on the phosphorous atom?

0

12
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Quiz 3 Q. 15: including the structure above, how many equivalent resonance structures exist for the phosphate ion?

4

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what is the empirical formula of a substance that contains 5.28g of C, 1.11 g of H, and 3.52 g of O?

C2H5O

14
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in a single reasonable Lewis dot structure, the polyatomic ion [CO3]^2- has _____ double bonds, _____ single bonds, and _____ lone pair(s) around the central atom

1,2,0

15
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Identify the ionic charge on Cr in the following compound: Cr2O3

3

16
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a double bond consists of ______ pair(s) of electrons

2

17
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what is the expected valence for the P atom

3

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Quiz 2 Q. 1: which atom would you expect to have the successive ionization energies shown below?

Si

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of the following, which gives the correct order for atomic radius for Mg, Na, P, and Si?

Na > Mg > Si > P

20
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the _______ quantum number describes the shape of an orbital

angular momentum

21
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Quiz 2 Q. 4: the arrow labeled (1) in the figure below is an _______ process and the arrow labeled (2) in the figure below is an _______ process

emission, absorption

22
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in a multielectron atom, which orbital will have the highest energy

3d

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Quiz 2 Q. 6: an orbital diagram for nitrogen (N) is incorrectly drawn below. which of the following principles does the orbital diagram violate

Heisenberg uncertainty

24
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an electron falls from the n=4 to n=2 shell in a H atom and releases light that appears blue-green with a wavelength of 486 nm. what is the energy of this photon in joules (J)?

4.09*10^-19J

25
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The atomic radius of main-group elements generally increases down a group because _______

electrons are placed in successively higher shells

26
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which set of quantum numbers best describes a 4p orbital?

4, 1, 0

27
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Iodine is best classified as a ____________.

halogen

28
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what is the wavelength of light (in nm) emitted from a traffic light having a frequency of 5.75*10^14s-1

521 nm

29
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the 4d-subshell can accommodate a maximum of ______ electrons

10

30
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Quiz 2 Q. 14: the image shown below represents a _______ orbital

p

31
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which of the following atoms would you expect to have the largest first ionization energy?

Cl

32
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how many total paired and unpaired electrons are in the 3d-subshell for the Ni atom?

6, 2

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which of the following correctly represents the electron affinity of the phosphorus atom?

P (g) + e- -> P- (g)

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Quiz 2 Q. 18: in the image below, the orbital with the highest subshell is _____

3s

35
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the condensed electron configuration for the Si atom is [Ne]3s^23p^2. how many core and valence electrons would you expect the Si atom to have?

10, 4

36
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which of the following is a valid set of four quantum numbers (n, l, ml, ms)?

2, 1, 0, +1/2

37
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electrons have a _____ charge, while neutrons have a ______ charge.

negative, neutral

38
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how many significant figures does the number 3.20*10^3 contain

3

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in 2009, a team from Northwestern University reported the preparation of a new "spongy" material composed of Ni, Mo, and S that excels at removing mercury (Hg) from water. The density of this spongy material is 0.20 g/cm^3 and its surface area is 1750 m^2/g. calculate the total surface area (in m^2) for 9.2 mg of this material.

16

40
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Nicotine (C10H14N2) is an addictive chemical that is found in tobacco. what is the molar mass (in g/mol) of the nicotine molecule?

162.236

41
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the molecular formula of aspartame, the aritficial sweetener marketed as NutraSweet is C14H18N2O5. how many kilograms (kg) are in 25.0 mols of aspartame? (The molar mass of aspartame is 294.307 g/mol)

7.36

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what atom or ion has 22 protons, 26 neutrons, and 21 electrons?

Ti+

43
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Quiz 1 Q. 8: which of the following particulate images best describes as a homogeneous mixture?

b

44
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Quiz 1 Q. 10: the mass of a rectangular block was determined to be 365.250 g and its length, width, and height are shown in the image below. what is the density (in g/cm^3) of this rectangular block reported to the correct number of significant figures?

2.60 g/cm^3

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which of the following symbols best represents the units of nanoseconds?

ns

46
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how many mols of oxygen are there in 0.125 moles of Ti2O3

0.375

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Quiz 1 Q. 13: consider the solution shown below. ________ is/are the solvent(s) and _______ is/are the solute(s).

solvent = methanol; solute = potassium and iodide

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what is the final concentration (in M) of a solution that was prepared by diluting 20.00 mL of a 0.125 M solution to a total of 100.00 mL?

0.0250

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a substance that can't be chemically broken down into simpler substances is defined as?

an element

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the atomic number (Z) is the number of _____ found in the nucleus of an atom?

protons

51
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to convert from mols to volume, which of the following conversion factors should you use?

molarity

52
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Quiz 1 Q. 20: based on the particulate level images shown below, which of the following solutions would you expect to have the highest concentration?

(ii)