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Which reagent is used to reduce nitrobenzene to aniline?
Sn/HCl
What is the product of Hofmann degradation of an amide?
Primary amine
Hofmann degradation results in the loss of how many carbon atoms from the original amide?
1
Which of the following is not involved in preparing aniline from nitrobenzene?
HNOâ
The reaction of CHâCO-NHâ with Brâ and KOH gives:
Methylamine
Disproportionation of HNOâ produces:
HNOâ and NO
In identifying tertiary amines, which compound is not formed?
Yellow precipitate
Which is a test used to differentiate primary, secondary, and tertiary amines?
HNOâ reaction
Zwitter ions contain:
Both +ve and -ve charges
In the basicity of aniline derivatives, which factor increases basic strength?
Electron-donating group
Which amine cannot form hydrogen bonds with water easily?
3° amine
Which test gives a foul 'dead fish' smell when reacting with 1° amine?
Carbylamine test
Azo compounds contain which bond?
N=N
The white precipitate formed by heating AgNOâ with chloroform is due to:
AgCl
What is the product of diazotization of aniline?
Benzenediazonium chloride
What is the product when benzenediazonium chloride reacts with phenol?
Azo dye
Which statement is true about chloroform under UV light with oxygen?
Ruins sample
Which intermediate is not seen in diazotization reaction?
Nitrasoamine
Which compound can be used to detect chloroform impurity?
AgNOâ
Whatâs formed when 2° amine reacts with HNOâ?
Nitrosoamine
How many types of amines can be differentiated using the HNOâ test?
3
In a 3° amine + HNOâ test, the product is:
Soluble ammonium salt
Which amine is least basic due to resonance effects?
Aniline
Which is used to prepare HNOâ freshly in lab?
NaNOâ + HCl
During diazotization, temperature should be kept around:
0â5°C