Reaction of ethanal with ammoniacal silver nitrate

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12 Terms

1
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Step 1
Add a drop of dilute sodium hydroxide to a solution of silver nitrate
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What is formed when sodium hydroxide is added to silver nitrate?
Brown precipitate of silver oxide
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Step 2
Add dilute ammonia until the brown precipitate dissolves
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What reagent is formed when dilute ammonia is added until brown precipitate is formed?
Tollens' reagent
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Step 3
Wash test tube with water then with propanone
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Step 4
Pour Tollens' reagent into the rinsed test tube
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Step 5
Add ethanal to the test tube and stand it in a beaker of boiling water
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Step 6
Note any observations
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What is observed when this experiment is carried out?
Silver mirror forms on inside surface of the test tube
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Draw a diagram of this experiment

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What is observed when this experiment is carried out with propanone?
No silver mirror forms
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Why is no silver mirror formed when this experiment is carried out with propanone?
Ketones are hard to oxidise