Intermolecular forces

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5 Terms

1
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What are characteristics of permanent dipole dipole forces

  • Stronger than London forces

  • Weaker than hydrogen bonding

  • Represented by delta positive/ negative

  • Only possible in molecules with permanent dipoles

2
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What are characteristics of hydrogen bonding

  • Strongest form of intermolecular force

  • Found in when hydrogen bonds to: oxygen, fluorine or nitrogen

  • Hydrogen will have a strong permanent dipole dipole with those elements

  • Hydrogen has a high charge density due to its small size

3
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How is strength of an intermolecular force determined

  • Number of electrons

  • More electrons means stronger induced dipole dipole forces

  • Larger fluctuations on electron density and leads to stronger temporary dipole and stronger dipole interactions

4
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What are characteristics of induced dipole dipole interactions

  • Partial charges exert onto nearby molecules

  • Partial charges can push or attract electrons in nearby molecules

  • Temporary dipoles will induce dipoles in nearby molecules

  • Induced dipoles will be attracted to the original dipole

5
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What are characteristics of temporary dipoles

  • Electron clouds around molecules are constantly moving

  • Partial charges can change very rapidly

  • Electron density is very unpredictable