Equilibrium

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19 Terms

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Dynamic Equilibrium

The rate of the forward reaction is equal to the rate of the reverse reaction

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Equilibrium Constant

The ratio of products to reactants when a chemical system is at equilibrium

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When K>1

Products are favoured

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When K=1

Approximately equal concentrations of reactants and products

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When K<1

Reactants are favoured

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Le Chatelier’s Principle

When a chemical system at equilibrium is disturbed by a change of concentration, temperature, or pressure, causing the system to shift

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Increasing concentration of product causes…

A shift to the reactants

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Decreasing the concentration of products causes…

A shift to the products

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Increasing concentration of reactants causes…

A shift to the products

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Decreasing the concentration of reactants causes…

A shift to the reactants

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When pressure is increased…

Shifts to the reaction with fewer moles of gas

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When pressure is decreased…

Shifts to the reaction with more moles of gas

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Endothermic 

Absorbs energy

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Exothermic 

Releases energy

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Endothermic Reaction

Increases in temperature, products, and K

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Exothermic Reaction

Increases in temperature, reactants, and decreases K

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When adding a catalyst…

Nothing happens, but helps speed up equilibrium

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When adding an Inert Gas at a constant volume…

Nothing happens

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When adding an inert gas at a constant pressure…

The system will shift towards the reaction with more moles of gas