Addition Reactions of Alkenes

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13 Terms

1
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Alkene + HBr ROOR

Hydrohalogenation AM

<p>Hydrohalogenation AM</p>
2
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Alkene + HX

Hydrohalogenation M

<p>Hydrohalogenation M</p>
3
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Alkene + 1) O3 2) DMS or Zn, HOAc

Ozonolysis (Ketone + aldehyde)

<p>Ozonolysis (Ketone + aldehyde)</p>
4
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1 Alkene + 1) OsO4 2)H2O2

Syn dihydroxylation

+ EN

1

<p>Syn dihydroxylation</p><p>+ EN</p><p>1</p>
5
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2 Alkene + KMnO4 NaOH, cold

Syn dihydroxylation

+ EN

2

<p>Syn dihydroxylation</p><p>+ EN</p><p>2</p>
6
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Alkene + 1) RCO3H 2) H30+

Anti dihydroxylation

+ EN (Anti)

<p>Anti dihydroxylation</p><p>+ EN (Anti)</p>
7
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Alkene + X2 (BR or Cl), H2O

Halohydrin formation

+ EN (Anti)

<p>Halohydrin formation</p><p>+ EN (Anti)</p>
8
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Alkene + Br2 or Cl2

Dihalogenation (Anti)

<p>Dihalogenation (Anti)</p>
9
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Alkene + H2 Pt (or Pd, Pd/C)

Catalytic Hydrogenation

<p>Catalytic Hydrogenation</p>
10
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Alkene + 1) BH3, THF 2)H2O2, NaOH

Hydroboration-oxidation

+ EN (AM, no rearrangements, syn)

<p>Hydroboration-oxidation</p><p>+ EN (AM, no rearrangements, syn)</p>
11
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Alkene + 1) Hg(OAc)2 H2O 2) NaBH4

oxymercuration-demercuration (M, no rearrangements)

<p>oxymercuration-demercuration (M, no rearrangements)</p>
12
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Alkene + H2O or Alcohol + catalytic acid

acid-catalyzed hydration M

13
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Alkene + 1) O3 2) H2O2 or 1) KMnO4, heat 2) H3O+

Ozonolysis (Ketone +Carboxylic acid)