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Dihydrolipoic acid, reduced (protonated)

CoA, reactions of thioesters


PLP, reactions of amino acids and C1
NAD+, oxidized (deprotonated), hydride carrier


TPP, reacts alpha-keto acids


PQQ, methanol oxidation
Topa, oxidation of Topa to TPQ

TPQ, co-factor amino oxidases

TTQ

Methanol

Formaldehyde

Methane

Formate
loss electrons, loss of hydrogen, or gain of oxygen
Oxidation
gain of electrons, gain of hydrogen, or loss of oxygen
Reduction
donates electrons to oxidizing agent, becomes oxidized
Reducing agent
accepts electrons from reducing agent, becomes reduced
Oxidizing agent
SAM, Fe-S enzyme cleaves to produce radical (H2C-Adolase), reactions of C1 groups

acyl transfer reactions, reactions of thioesters
lipoate importance
alcohol to carbonyl oxidation reaction
NAD+/NADP+
pterin, reactions of O2
molybdopterin, redox reactions

reactions of C1 groups
folates importance
folic acid

dihydrofolate

tetrahydrofolate

biotin, carboxylation reactions

participate in either 1e- or 2e- redox reactions, reactions of O2
importance flavins
flavin (oxidized, depronoated)

dihydroflavin (reduced, protonated)

cyanocobalamin (Vitamin B12)

Methylcobalamin (Methyl B12) (folate deliver methyl)

Hydroxocobalamin (Cob(III)alamin)

Adenosylcobalamin (Co-enzyme b12)

carbonyl to alcohol reduction
NADH/NADPH
Quinones, reactions of O2 and amino acids

Reaction of C1 groups
B12 importance
riboflavin, reacts o2

FMN/FMNH

FAD/FADH
