Intermolecular Forces

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Intramolecular Forces compared to Intermolecular Forces; Dispersion Forces; Interactions Involving Polar Molecules; Vapor Pressure of Pure Liquids; Phase Diagrams: Intermolecular Forces at Work

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9 Terms

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Induced dipole 

the separation of charge produced in an atom or molecule by a momentary uneven distribution of electrons.

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Dispersion force (London force)

an intermolecular force between molecules caused by the presence of temporary dipoles in the molecules.

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Polarizability

the relative ease with which the electron clouds surrounding the nuclei of individual atoms or molecules can be distorted, thereby inducing temporary dipoles.

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ion-dipole interaction

an attractive force between an ion and a molecule that has a permanent dipole moment.

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sphere of hydration 

the cluster of water molecules surrounding an ion in aqueous solution; the general term applied to such a cluster forming in any solvent is sphere solvation.

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dipole-dipole interaction 

an attractive force between polar molecules 

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dipole-induced dipole interaction 

an attraction between a polar molecule and the oppositely charged pole it temporarily induces in another molecule

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What are intramolecular forces?

They are forces in the molecule, like the electrical forces between electron pairs, that determine molecular shape

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What are intramolecular forces?

They are the electrical forces between molecules and ions; they aren’t as strong in energy, but they are impactful to the properties of all substances.