Enthalpy definitions.

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15 Terms

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Enthalpy of formation.

The enthalpy change when one mole of a compound is formed from its elements in their standard states.

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Enthalpy of combustion

The enthalpy change when one mole of a substance undergoes complete combustion with oxygen under standard conditions and with all substances in their standard states.

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Enthalpy of neutralization

Enthalpy change when 1 mole of a water is formed in a reaction between an acid and an alkali under standard conditions and all substances are in their standard states.

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Ionisation Enthalpy (1st)

Enthalpy change when each atom in one mole of gaseous atoms loses 1 electron to form one mole of gaseous 1+ cations in their gaseous state.

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Ionisation Enthalpy (2nd)

Enthalpy change when each atom in one mole of gaseous +1 ions loses 1 electron to form one mole of gaseous 2+ cations in their gaseous state.

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Electron Affinity (1st)

Enthalpy change when each atom in one mole of gaseous atoms gains 1 electron to form one mole of gaseous 1- anions in their gaseous state.

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Electron Affinity (2nd)

Enthalpy change when each atom in one mole of gaseous 1- anions gains 1 electron to form one mole of gaseous 2- anions in their gaseous state.

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Enthalpy of Atomisation

Enthalpy change when one mole of gaseous atoms are produced from an element in its standard state.

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Hydration Enthalpy

Enthalpy change when one mole of gaseous ions is dissolved in water.

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Enthalpy of Solution

Enthalpy change when 1 mole of an ionic solid dissolves in an amount of water large enough so that the dissolved ions are separated enough not to interact with each other.

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Bond dissociation Enthalpy

Enthalpy change when one mole of covalent bonds is broken in the gaseous state.

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Lattice Enthalpy of formation

Enthalpy change when 1 mole of a solid ionic compound is formed from its constituent ions in the gas phase.

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Lattice Enthalpy of dissociation.

Enthalpy change When 1 mole of its solid ionic compound is broken up into its constituent elements in the gas phase.

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Enthalpy of vapourisation

Enthalpy change when 1 mole of liquid is turned into gas.

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Enthalpy of Fusion

Enthalpy change when 1 mole of a solid is turned into a liquid.