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phase
a region in a material that has a uniform structure, properties, and composition and maintains a distinct boundary with other unlike phases
cooling curve
temperature of molten metal vs time as it cools to room temp
hypoeutectic alloys
alloys with Sn wt% greater than 19.2 and less than 61.9
hypereutectic alloys
alloys with Sn wt% greater than 61.9 and less than 97.5
peritectic reaction
liquid phase reacts with a solid phase to form a new and different solid phase
monotectic reaction
liquid phase transforms into solid phase and another liquid
terminal phases
phases that occur at the end of phase diagrams
intermediate phases
phases that occur in a composition range inside phase diagram
pig iron
iron ore mixed with coke inside a blast furnace
austenitizing
eutectoid steel heated slightly abobe 727 C and held there for sufficient time
martensite
a metastable phase consisting of super saturated interstitial solid solution of C in BCC
full anneal heat treatment
softens the steel to its lowest strength and grows large equiaxed grains
process anneal heat treatment
relieves the internal residual stresses through realignment of dislocations
normalization heat treatment
refines the grain structure, produces a stronger steel
precipitation strengthening heat treatments
creates fine dispersion of precipitated particles in the metal which hinder dislocation
steps: solution heat treatment, quenching, aging
properties of aluminum
low density, corrosion resistance, high alloy strength, nontoxic, and good electrical properties
properties of Copper
good electrical and thermal conduction, ease of fabrication, corrosion resistance, medium strength
properties of stainless steel
excellent corrosion resistance because of chromium oxide surface, high strength and durability, and good heat resistance
cast iron properties
easily melted, very fluid, low shrinkage, easily machinable, low impact resistance and ductility
amorphous metals
atoms arranged in random manner in metals under special circumstances (Ti)
properties of titanium alloys
low density and high strength, expensive, superior corrosion resistance, special technique needed to work with metal, HCP at room temp —> BCC at 883 C
steps of chain polymerization
initiation, propagation, termination
vinyl polymers
one of the hydrogen atoms is replaced by another atom or group of atoms
vinylidene polymers
both hydrogen atoms on the carbon chain are replaced by another atom or group of atoms
homopolymers
polymer chain made up of single repeating units
copolymers
polymer chains made up of two or more repeating units
random copolymers
different monomers randomly arranged in chains (ABBABAAABAA)
alternating copolymers
definite ordered alterations of monomers (ABABABABAB)
block copolymers
different monomers arranged in long blocks (AAAAAABBBBBB)
graft copolymers
one type of monomer grafted to long chain of another
injection molding
plastic granules or pellets are transformed into sheets, rods, sections, etc to manufacture thermoplastic components
injection molding
pros: high quality parts, rapid production rate, low labor cost, good surface finish, highly automated, intricate shapes
cons: high cost of machines, process requires close monitoring and control
extrusion
melted plastic force by rotating screw through a opening and used to produce pipes, rods, etc
blow molding
compressed air is blown into heated cylinder or pipe of plastic to press it against the wall of mold
thermoforming
heated plastic sheet is forced into contours of a mold by pressure
compression molding
preheated thermosetting resins are formed into solid parts
transfer molding
a plunger forces the preheated plastic resin, placed outside mold, into mold cavities for thermosetting plastics
polyethylene
clear whitish translucent thermoplastic
types: low density, high density, linear low density
polyvinylchloride (PVC)
a noon-crystalline or amorphous thermoplastic and doesn’t recrystallize
polypropylene (PP)
third most used thermoplastic and lowest in cost, low density, good chemical resistance, moisture resistance and heat resistance
applications: housewares, appliances, packaging, lab ware, bottles
ABS
high impact applications, mixture of three monomers
applications: pipe and fittings, automotive parts, computer and telephone housings
engineering thermoplastics
low densit, low tensile strength, high insulation, good corrosion resistance
properties of nylons (polyamides)
high strength due to hydrogen bonding, flexibility, low melt viscosity, high lubricity
applications: electrical equipment, gears, auto parts, packaging
polycarbonate (PC)
high strengths, toughness and dimensional stability, very high impact strength, high heat deflection temp, resistance to corrosion
applications: precision parts, cams, gears, helmets, power tool housing
thermosetting plastics
high thermal and dimensional stability , rigidity, resistance to creep, light weight
ceramics
inorganic, nonmetallic, strong ionic or covalent bonds, excellent electrical insulators, excellent heat insulators, very hard, highly brittle, low toughness, high melting temp
graphite
carbon allotrope, layred structue with carbon atoms strongly bonded in hexagonal arrays
properties: high strength and conductivity, excellent lubricating properties
diamond
carbon allotrope, cubic structure
properties: stiffest, hardest, and least compressible material made by nature, high thermal conductivity but minimal electrical conductivity
forming processes of ceramics
pressing, slip casting, and extrusion
slip casting
slip poured into mold, draining mold, dried and fired int mold, top trimmed
extrusion
ceramic precursor is forced through hard steel ot alloy die by a motor divern augur
conventional ceramics
clay, silica, feldspar (potassium)
clay
provides workability and hardness in material
silica (flint quartz)
high melting temp and is refractory component of traditional ceramics
Feldspar or Potash (potassium)
low melting temperature and makes a glass when the ceramic mix is fired.
engineering ceramics
alumina, silicon nitride, silicon carbide, zirconia
mechanical properties of ceramics
generally brittle, tensile strength lower than compressive, less dense than most metals, low toughness, low thermal conductivity, and high heat resistance
composites
pros: light weight —> low density, high strength and stiffness, high specific modulus and specific strength, controlled anisotropy
cons: low ductility, low resistance to impact damage
glass fibers
high strength-to-weight ratio, good dimensional stability, good temp, and corrsion resistant, and low cost
carbon fibers
lightweight with very high strength and stiffness
carbon fiber manufacturing
stabilization, carbonization, graphization
lamina
unidirectional layer of fiber-reinforced polymer, strong and stiff in fiber direction
concrete
flexible, economical, fire resistant, durable, fabricated on site, high compressible but low tensile strength
wood
naturally occurring composite with polymeric material
softwoods
seed is exposed, retain its leaves, and physically soft
hardwoods
seeds are covered, sheds leaves annually