Chapter 17 Aqueous Equilibria - Student Notes

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42 Terms

1

Titration

A procedure for determining the concentration of a solution by allowing a measured volume to react with another solution of known concentration.

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2

Equivalence Point

The point in a titration at which the number of moles of titrant added equals the number of moles of analyte in the sample.

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3

pKa

The negative logarithm of the acid dissociation constant (Ka), which indicates the strength of an acid.

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4

Buffer Solutions

A solution that resists changes in pH upon the addition of small amounts of acid or base.

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5

Common-Ion Effect

The shift in the position of an equilibrium caused by the addition of an ion that is a part of the equilibrium.

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6

Henderson-Hasselbalch Equation

An equation used to estimate the pH of a buffer solution: pH = pKa + log([A-]/[HA]).

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7

Weak Acid

An acid that partially dissociates in solution.

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8

Strong Acid

An acid that completely dissociates in solution.

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9

Net Ionic Equation

An equation that shows only the species that participate in a reaction, excluding spectator ions.

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10

Buffer Capacity

A measure of the ability of a buffer to resist changes in pH upon the addition of an acid or base.

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11

Acid-Base Reaction

A chemical reaction that occurs between an acid and a base.

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12

Titrand

The solution of unknown concentration being analyzed in a titration.

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13

Titrant

The solution of known concentration that is added in a titration.

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14

Conjugate Base

The species that remains after an acid has donated a proton.

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15

Conjugate Acid

The species formed when a base accepts a proton from an acid.

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16

Saturated Solution

A solution containing the maximum amount of solute that can dissolve at a given temperature.

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17

Solubility-Product Constant (Ksp)

The equilibrium constant for a solid compound dissolving in water.

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18

Le ChĆ¢telierā€™s Principle

A principle stating that if a system at equilibrium is disturbed, the system shifts in a direction that counteracts the disturbance.

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19

pH

A measure of the acidity or basicity of a solution.

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20

pOH

A measure of the hydroxide ion concentration in a solution, calculated as pOH = -log[OH-].

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21

Diprotic Acid

An acid capable of donating two protons (H+) per molecule.

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22

What is titration?

A procedure for determining the concentration of a solution by allowing a measured volume to react with another solution of known concentration.

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23

What is the equivalence point in titration?

The point at which the number of moles of titrant added equals the number of moles of analyte in the sample.

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24

What is pKa?

The negative logarithm of the acid dissociation constant (Ka), which indicates the strength of an acid.

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25

Define buffer solutions.

A solution that resists changes in pH upon the addition of small amounts of acid or base.

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26

What is the common-ion effect?

The shift in the position of an equilibrium caused by the addition of an ion that is a part of the equilibrium.

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27

What does the Henderson-Hasselbalch equation calculate?

It estimates the pH of a buffer solution: pH = pKa + log([A-]/[HA]).

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28

What is a weak acid?

An acid that partially dissociates in solution.

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29

What is a strong acid?

An acid that completely dissociates in solution.

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30

What is a net ionic equation?

An equation that shows only the species that participate in a reaction, excluding spectator ions.

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31

What is buffer capacity?

A measure of the ability of a buffer to resist changes in pH upon the addition of an acid or base.

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32

What happens in an acid-base reaction?

A chemical reaction that occurs between an acid and a base.

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33

What is a titrand?

The solution of unknown concentration being analyzed in a titration.

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34

What is a titrant?

The solution of known concentration that is added in a titration.

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35

What is a conjugate base?

The species that remains after an acid has donated a proton.

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36

What is a conjugate acid?

The species formed when a base accepts a proton from an acid.

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37

What is a saturated solution?

A solution containing the maximum amount of solute that can dissolve at a given temperature.

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38

What is the solubility-product constant (Ksp)?

The equilibrium constant for a solid compound dissolving in water.

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39

What is Le ChĆ¢telierā€™s Principle?

A principle stating that if a system at equilibrium is disturbed, the system shifts in a direction that counteracts the disturbance.

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40

What does pH measure?

A measure of the acidity or basicity of a solution.

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41

What does pOH measure?

A measure of the hydroxide ion concentration in a solution, calculated as pOH = -log[OH-].

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42

What is a diprotic acid?

An acid capable of donating two protons (H+) per molecule.

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