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energy within light is captured and used to syntheiss carbohydrates
photosynthesis
chemical formula for photosynthesis
CO2+ 2H2O + light --> CH2O + O2 +H2O
in Photosynthesis CO2 is _______ and O2 is ______________
reduced; oxidized
organelles in plants and alge that carry out photosynthesis
Chloroplast
green pigment
chlorophyll
What are the two stages of photosynthesis
Light Reactions and Calvin Cycle
this takes place in the thylakoid membranes to produce ATP, NADPH, and O2
Light reactions
O2 is exhaled by plants in the _____________
stomata
carbohydrates are made here; occurs in the Stroma; uses ATP and NADPH to incorporate CO2 into organic molecules
Calvin Cycle
After an electron absorbs energy it___________
is excited and unstable
Excited electrons are ___________ or ________ by another molecule
transferred to or captured
absorption of wavelengths by different pigments in the plant
absorption spectrum
rate of photosynthesis by whole plant at specific wave lengths
Action spectrum
a complex of proteins and pigment molecules
photosystems
The photosytems are located in the
thylakoid membrane
What are the two main components of Photosystem 1
Light-harvesting complex (antenna complex)
Reaction center
directly absorbs photons and transfers energy to P680 (chlorophyll molecule)
light-harvesting complex
P680 becomes excited and unstable so an electron is transferred to primary electron acceptor. Then it removes electrons from water to restore the P680
Reaction center
this is a redox machine where electrons move from primary electron acceptor in PSII to P700 in the reaction center of PS1
Photosystem I1
uses chemiosmosis to produce ATP
Photosytem II
Key role is to make NADH; light harvsting complex abosrbs photons and transfers energy to P700
Photosytem I
_____ is produced in the thylakoid lumen by oxidation of H2O from PSII
O2
_____ is produced in stroma by H+ electrochemical gradient
ATP
the splitting of water places H+ in the
lumen
Formation of ______________consumes H+ in the stroma from
NADPH
_____ is produced in the stroma from high energy electrons that start in ______ and are boosted in ____________
NADPH; PSII; PSI
in the Calvin Cycle ____ and _____ are used to make carbohydrates
ATP and NADH
Fixation (incorporation of CO2) requires a large input of ___________
energy
in the calvin cycle for every 6CO2 incorporated, _____ ATP and _____ are used
18; 12
CO2 is reduced to _______ and this is used to make
G3P; glucose
What are the three parts of the calvin cycle ?
Carbon fixation, reduction and carbohydrate production, regeneration of ribulose biphosphate (RuBP)
the regeneration of ________ keeps the cycle going
RuBP
a process by which living organisms obtain energy from organic molecules
cellular respiration
What is the primary aim of cellular respiration?
to make ATP and NADH
Aerobic respiration uses
oxygen
in an Aerobic respiration reaction O2 is __________ and CO2 is ________
consumed; released
What is the chemical formula for cellular respiration?
organic molecule+ O2--> CO2 + H2O + Energy
Name the 4 metabolic pathways in Glucose Metabolism
Glycolysis, breakdown of pyruvate, citric acid cycle, oxidative phosphoralyation
Glycolysis can occur with or withour what
oxygen
What are the 3 phases of the 10 steps in glycolysis
Energy investment (uses ATP), Cleavage ( 1 hexos-> trioses), energy liberation (net 2 ATP and 2 NADH)
The break down of pyruvate occurs where?
mitochondrial matrix
Pyruvate is broken down by.....
Pyruvate dehydrogenase
A molecule of _________ is removed from each pyruvate
CO2
The remaining acetyl group attached to a Coa to make a ....
coenzyme or acetyl CoA
______ is produced from each pyruvate
1
particular molecuels enter while others leave, involving a series of organic molecules regenerating with each cycle
metabolic cycle (citric acid cycle)
In the Citric Acid Cycle, Acetyl is removed from the Acetyl CoA and attach to oxaloacatate to form______
citric acid
The products of the Citric Acid Cycle are....
2 CO2
1 ATP
3NADH
1 FADH2
_______________ is regenerated to start the cycle again
oxaloacetate
_______ are removed from NADH and FADH2 to make ATP during Oxidative phosphorylation
high energy electrons
Oxidative phosphorylation requires
oxygen
oxidative process involves _________
electron transport chain
Phosphorylation occurs by
ATP synthase
a group of protein complexes and small organic molecules embedded in the inner mitochondrial membrane
electron transport chain
The electron transport chain can donate electrons in a linear manner in a series of _________
redox reactions
Movement of electrons generates __________ and _________ with an excess of _____ charge outside of the matrix
H+ electrochemical gradient / proton- motive force; positive
Movement from NADH to O2 is a very large ....
free energy change
Free energy change is spontaneous in ______
forward direction
Free energy change is ________________
highly exergonic
Some enrgy used to _______ across inner mitochondrial membrane and create __________
pump H+; H+ electrochemical gradient
Enzyme harnesses free energy as H+ glow through membrane embedded region
ATP Synthase
H+ electrochemical gradient or protn motive force is converted to chemical bond energy in ATP
energy conversion
ATP synthase acts as a __________ as it makes ATP while spinning
Rotary Machine
What are other organic molecules that can be used for energy?
carbohydrates, proteins, and fats
Other organic molecules enter into _________ or citric acid cycle at different points
glycolysis
________ can also be used to make other molecules (anabolism)
Metabolism
got enviroments that lack oxygen or during oxygen deficits
anaerobic metabolism
What are the 2 Strategies for anaerobic metabolism?
Use substances other than oxygen as a final electron acceptor in electron transport chain
Make ATP by glycolysis but must regenerate NAD+
pyruvaate can be converted to ___________ in muscles or ___________ in yeast
lactate (lactic acid); ethanol
produces far less ATP (2 versus 34-38 per glucose) (type of anaerobic metabolism)
fermentation
An anaerobic (without oxygen) cellular process in which an organic food is converted into simpler compounds, and chemical energy (ATP) is produced
fermentation
what are the starting materials for an Anaerobic Metabolism reaction?
What are the ending materials of an Anaerobic Reaction?
What are the products for the Citric acid cycle
3 NADH, 1 FADH2, 1 guanine triphosphate (G3P), 3 hydrogens
what does glycolysis produce
pyruvate, NADH, and ATP
Glycolysis starts with ....
Glucose, NAD, and ATP
The breakdown of Pyruvate produces ....
NADH
oxidative phosphorylation produces ....
ATP and water
the ability to promote change
energy
name the 2 forms of energy
potential; kinetic
associated with movement
Kinetic
due to structure or location
potential
energy in molecular bonds
chemical energy (type of potential energy)
1st law of thermodynamics
Law of conservation of energy; energy cant be created or destroyed but may be transferred or transformed
2nd law of thermodynamics
energy transfer or transformation from one form to another increases entropy or degree of disorder of a system
What do the letters in H=G+TS stand for
H- enthalpy or total energy
G- free energy
S- entropy or disorder
T- absolute temperature in kelvin
Energy requirement of reaction depends on the change in what?
Free energy
describes a system of energy that has a negative free energy change and products have less free energy than reactants ( going down hill) as free energy exits; spontaneous
exergonic
describes a system of energy that has a postitive free energy change and products have more free energy than reactants (going up hill) as free energy enters; not spontaneous
endergonic
Term that has a free energy change of -7.3kcal/mol; reaction favors formation of products; energy liberated can drive a varity of cellular processes
ATP Hydrolysis
With ATP hydrolysis, an endergonic reaction can be coupled to an _________________
exergonic reactions
Endergonic reaction will occur if net free energy change for both processes is ____________
negative
a spontaneous reaction is not necessarily ____________
fast
agent that speeds up the rate of a chemical reaction without being consumed during a reaction
catalysts
protein that catalysts in living cells
enzyme
allows for a "boos" of energy to start a reaction, molecules to get close enough to cause bond arrangement, and allows for molecules to achieve transition state where bonds are stretched
Activation energy
What are the 2 Common ways to overcome activation energy?
Large amounts of heat
Using enzymes to lower activation energy
____________ in reactants make it easier to achieve transition state and lower activation energy
straining bonds
_________ together facilitate bonding and lowers activation energy
positioning bonds
______________ allows for a direct participation through very temporary bonding
Changing local environment