Amines:

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AQA Amines topic

23 Terms

1

Amines

Compounds derived from ammonia molecules that contain a nitrogen atom.

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2

Primary Amines

Amines where one hydrogen in ammonia is replaced with an alkyl group.

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3

Secondary Amines

Amines where two hydrogens in ammonia are replaced with alkyl groups.

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4

Tertiary Amines

Amines where all three hydrogens in ammonia are replaced with alkyl groups.

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5

Quaternary Amines

Amines with four alkyl groups around the nitrogen atom, which carries a positive charge.

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6

Aromatic Amines

Primary amines that contain a benzene ring.

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7

Aliphatic Amines

Non-aromatic amines, which do not contain a benzene ring.

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8

Cationic Surfactants

Quaternary ammonia salts used in cleaning products with a long hydrocarbon tail.

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9

Tetramethylammonium Chloride

An example of a cationic surfactant.

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10

Emulsion

A mixture that allows oil and water to mix, facilitated by surfactants.

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11

Static Removal

The process by which positive ammonium ions attract negatively charged hair and fibers to eliminate static.

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12

Amines as Bases

Compounds that accept H+ ions due to a lone pair of electrons on nitrogen.

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13

Coordinate Bond

A bond formed when both electrons come from the lone pair of an amine.

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14

Electron Density

The availability of electrons on nitrogen, affecting the strength of the base.

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15

Aromatic Amines

Less basic due to electron withdrawal into the benzene ring.

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16

Aliphatic Amines

More basic due to electron donation from alkyl groups.

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17

Nucleophiles

Compounds that can donate a lone pair of electrons, such as amines.

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18

Preparation of Aliphatic Amines

Achieved by reacting halogenoalkanes with excess ammonia or reducing nitriles.

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19

Catalytic Hydrogenation

A method to produce primary amines using hydrogen gas and a nickel or platinum catalyst.

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20

Nitrobenzene Reduction

The process of converting nitrobenzene to an aromatic amine.

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21

Amides

Derivatives of carboxylic acids with the functional group -CONH2.

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22

N-Substituted Amides

Amides where one hydrogen is replaced with an alkyl group.

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23

Production of Amides

Made from the reaction of an acyl chloride with ammonia.

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