Esterification

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20 Terms

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Ester stretch

1735

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Weak aromatic ring

1660-2000

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Medium aromatic ring

1450-1600

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Aqueous layer

Sulfuric acid majority of methanol

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Organic layer

Dichloromethane

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Neutralize aqueous layer with

Sodium carbonate (a base Na2CO3)

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Catalyst needed for esterification

Strong acid

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1st step esterification

Oxygen gets protonated by H3O/acid

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2nd step of esterification

Oxygen in alcohol attacks carbonyl carbon, double bond in carbonyl breaks, OH attaches

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3rd step

Proton transfer attacks OH on the end creating water and leaves. Carbonyl reforms

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4th step

Water protonates carbonyl OH creates water

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Dehydration mechanisms step 1

OH protonates acid

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Dehydration step 2

Water attacks hydrogen and hydrogen bond forms alkene. Water leaves

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Step 3 dehydration

Alkene is formed

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Grignard reaction step 1

Grignard attacks carbonyl carbon and bond from O in ester attacks O causing it to leave

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Grignard reaction step 2

Carbonyl oxygen breaks double bond and pronates acid

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Grignard reaction step 3

2nd grignard attacks carbonyl carbon, final product is formed

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Friedel-Crafts reaction step 1

Alcohol protonates acid creates water

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Friedel-Crafts reaction step 2

Water leaves and alkene bond from ring attacks center carbon

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Friedel-Crafts reaction step 3

Alkene splits, alcohol group is attached to the ring and water attacks hydrogen, hydrogen leaves and deforms double bond