Understanding Stereoisomerism and Geometric Isomerism

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25 Terms

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Stereoisomerism

Isomerism with same formula, different 3D orientations.

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Stereoisomers

Compounds exhibiting stereoisomerism characteristics.

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Geometric Isomerism

Also known as cis-trans isomerism in compounds.

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Cis-Trans Isomerism

Isomers with different spatial arrangements of atoms.

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Restricted Rotation

Limited movement around bonds in a molecule.

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Cis Isomer

Functional groups on the same side of a bond.

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Trans Isomer

Functional groups on opposite sides of a bond.

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Double Bonds

Bonds preventing rotation, leading to isomerism.

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Ring Structures

Molecules with restricted bond rotation due to rings.

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Maleic Acid

Cis isomer of butenedioic acid with distinct properties.

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Fumaric Acid

Trans isomer of butenedioic acid with different properties.

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Acyclic Compounds

Non-cyclic compounds that can exhibit geometric isomerism.

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Cis-1,2-Dichlorocyclohexane

Achiral compound with an internal plane of symmetry.

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Trans-1,2-Dichlorocyclohexane

Chiral compound without a plane of symmetry.

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E/Z Notation

System for naming isomers with multiple substituents.

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Cahn-Ingold-Prelog Rules

Priority rules for determining E/Z configurations.

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Z Isomer

Higher-priority substituents on the same side.

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E Isomer

Higher-priority substituents on opposite sides.

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Trans Fats

Produced by hydrogenation, harmful to health.

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Hydrogenation

Process converting unsaturated fats to saturated fats.

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Shelf Life

Duration a product remains usable or safe.

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Chiral

Molecules that cannot be superimposed on their mirror images.

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Boiling Point

Temperature at which a substance transitions to gas.

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2-Pentene

Example of a compound with cis/trans isomerism.

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Structural Formula

Representation showing how atoms are arranged in a molecule.