Chemical Kinetics and Reaction Mechanisms

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These flashcards cover key terms and concepts related to chemical kinetics and reaction mechanisms, as highlighted in the lecture notes.

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11 Terms

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Overall Reaction

H₂ + 2 ICl -> I₂ + 2 HCl

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Rate Law

Rate = k [H₂][ICl]

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Elementary Step 1

H₂ + ICl -> HI + HCl

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Elementary Step 2

HI + ICl -> I₂ + HCl

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Intermediates

Substances that are produced in one elementary step and consumed in another.

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Bimolecular Reaction

A reaction that involves two reactants.

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Half-Life Calculation

The time required for the concentration of a reactant to decrease to half its initial value.

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Final Concentration Calculation

The final concentration after a given time based on initial concentration and rate constants.

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Rate Determining Step

The slowest elementary step in a reaction mechanism which determines the rate of the overall reaction.

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Second Order Reaction

A reaction whose rate depends on the square of the concentration of one reactant or the product of the concentrations of two reactants.

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Straight Line Plot

A plot of concentration vs. time that reflects a zero-order reaction.